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D - "glucose"overset("Tollen's reagent")...

`D - "glucose"overset("Tollen's reagent")rarr(A),`
`D-"glucose"overset(Br_(2)-"water")rarr (B)`
(A) and (B) are :

A

gluconic acid, gluconic acid

B

glucaric acid, gluconic acid

C

salt of gluconic acid, gluconic acid

D

salt of gluconic acid, glucaric acid

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The correct Answer is:
To solve the question, we need to determine the products (A) and (B) formed when D-glucose reacts with Tollen's reagent and bromine water, respectively. ### Step 1: Understanding D-Glucose Structure D-glucose is an aldohexose sugar with the following structure: - The molecular formula is C₆H₁₂O₆. - The structure includes an aldehyde group (CHO) at one end and five hydroxyl (OH) groups. ### Step 2: Reaction of D-Glucose with Tollen's Reagent When D-glucose reacts with Tollen's reagent (Ag(NH₃)₂⁺ in the presence of OH⁻), the aldehyde group (CHO) is oxidized to a carboxylic acid (COOH). The reaction can be summarized as follows: - The aldehyde group (CHO) is converted to a carboxylate ion (COO⁻). - The product formed is gluconic acid (C₆H₁₂O₇) in the form of its salt. **Product A:** The product (A) formed from the reaction of D-glucose with Tollen's reagent is **gluconic acid**. ### Step 3: Reaction of D-Glucose with Bromine Water Bromine water (Br₂ in water) is a mild oxidizing agent. When D-glucose reacts with bromine water, the aldehyde group (CHO) is again oxidized to a carboxylic acid (COOH). The remaining hydroxymethyl group (CH₂OH) remains unchanged. **Product B:** The product (B) formed from the reaction of D-glucose with bromine water is also **gluconic acid**. ### Final Answer: - (A) is **gluconic acid** (from Tollen's reagent). - (B) is **gluconic acid** (from bromine water). ---
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