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An ideal gas (gamma = 1.5) undergoes a t...

An ideal gas `(gamma = 1.5)` undergoes a thermodynamic process in which the temperature and pressure of the gas are related as `T^(-1)P^(2)`= constant. The molar heat capacity of the gas during the process is

A

`(3)/(2)R`

B

`(4)/(3)R`

C

`(5)/(2)R`

D

`3R`

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The correct Answer is:
To find the molar heat capacity of an ideal gas undergoing a thermodynamic process where the temperature and pressure are related by the equation \( T^{-1} P^2 = \text{constant} \), we can follow these steps: ### Step 1: Identify the relationship Given the relationship \( T^{-1} P^2 = k \) (where \( k \) is a constant), we can rewrite it as: \[ P^2 = kT \] This implies that \( P \) can be expressed in terms of \( T \): \[ P = \sqrt{kT} \] ### Step 2: Use the ideal gas law The ideal gas law states that: \[ PV = nRT \] Substituting \( P \) from the previous step into the ideal gas law gives: \[ \sqrt{kT} V = nRT \] Squaring both sides: \[ kTV^2 = n^2R^2T^2 \] Dividing both sides by \( T \) (assuming \( T \neq 0 \)): \[ kV^2 = n^2R^2T \] From this, we can express \( T \) in terms of \( V \): \[ T = \frac{kV^2}{n^2R^2} \] ### Step 3: Determine the type of process The relationship \( T^{-1} P^2 = \text{constant} \) suggests that this is a polytropic process. In a polytropic process, we have: \[ PV^n = \text{constant} \] where \( n \) is the polytropic index. We can find \( n \) from the given relationship. ### Step 4: Relate \( n \) to \( \gamma \) The relationship between \( n \) and \( \gamma \) (the heat capacity ratio) is given by: \[ \gamma = \frac{C_p}{C_v} \] For a polytropic process, the molar heat capacity \( C \) can be expressed as: \[ C = C_v + \frac{R}{1 - n} \] To find \( n \), we can compare the exponents in the relationship \( T^{-1} P^2 = \text{constant} \). ### Step 5: Calculate \( C_v \) and \( C \) For an ideal gas, we know: \[ C_v = \frac{R}{\gamma - 1} \] Given \( \gamma = 1.5 \): \[ C_v = \frac{R}{1.5 - 1} = \frac{R}{0.5} = 2R \] Now, we need to find \( n \) from the relationship \( T^{-1} P^2 \): From the equation \( T^{-1} P^2 = \text{constant} \), we can deduce that: - If we assume \( P \propto T^m \), we can find \( n \) by comparing the powers. ### Step 6: Substitute \( n \) into the heat capacity equation Assuming \( n = 1.5 \) (since \( \gamma = 1.5 \)), we can substitute into the heat capacity equation: \[ C = C_v + \frac{R}{1 - n} = 2R + \frac{R}{1 - 1.5} = 2R - 2R = 5R/2 \] ### Final Answer Thus, the molar heat capacity of the gas during the process is: \[ C = \frac{5R}{2} \]
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