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In 1 L saturated solution of AgCl[K(sp)(...

In 1 L saturated solution of `AgCl[K_(sp)(AgCl)=1.6xx10^(-19)], 0.1" mol of "CuCl[K_(sp)(CuCl)=1.0xx10^(-6)]`
is added. The resultant concentration of `Ag^(+)` in the solution is `1.6xx10^(-x)`. The value of ''x'' is

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To solve the problem, we need to determine the concentration of \( Ag^+ \) ions in a saturated solution of \( AgCl \) after adding \( 0.1 \) mol of \( CuCl \). We will use the solubility product constants (\( K_{sp} \)) for both salts to find the answer. ### Step-by-Step Solution: 1. **Identify the Solubility Product Constants**: - For \( AgCl \), \( K_{sp}(AgCl) = 1.6 \times 10^{-10} \). - For \( CuCl \), \( K_{sp}(CuCl) = 1.0 \times 10^{-6} \). 2. **Dissociation of \( CuCl \)**: - When \( CuCl \) dissolves, it dissociates into \( Cu^+ \) and \( Cl^- \) ions: \[ CuCl \rightleftharpoons Cu^+ + Cl^- \] - Since \( 0.1 \) mol of \( CuCl \) is added to \( 1 \) L of solution, the concentration of \( Cl^- \) ions from \( CuCl \) will be: \[ [Cl^-] = 0.1 \, \text{mol/L} \] 3. **Calculate the Concentration of \( Cl^- \)**: - The concentration of \( Cl^- \) from \( CuCl \) is \( 0.1 \, \text{mol/L} \). 4. **Use the \( K_{sp} \) Expression for \( AgCl \)**: - The solubility product expression for \( AgCl \) is: \[ K_{sp}(AgCl) = [Ag^+][Cl^-] \] - Rearranging this gives: \[ [Ag^+] = \frac{K_{sp}(AgCl)}{[Cl^-]} \] 5. **Substituting Values**: - Substitute the known values into the equation: \[ [Ag^+] = \frac{1.6 \times 10^{-10}}{0.1} \] - Calculate: \[ [Ag^+] = 1.6 \times 10^{-10} \times 10 = 1.6 \times 10^{-9} \, \text{mol/L} \] 6. **Expressing in the Required Form**: - The problem states that the resultant concentration of \( Ag^+ \) is \( 1.6 \times 10^{-x} \). - From our calculation, we have: \[ 1.6 \times 10^{-9} = 1.6 \times 10^{-x} \] - Therefore, \( x = 9 \). ### Final Answer: The value of \( x \) is \( 9 \).
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In 1L saturated solution of AgCI [K_(sp) (AgCI) = 1.6 xx 10^(-10)], 0.1 mol of CuCI [K_(sp)(CuCI) = 1.0 xx 10^(-6)] is added. The resultant concentration of Ag^(+) in the solution is 1.6 xx 10^(-x) . The value of "x" is.

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