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Which product will be obtained by Gridna...

Which product will be obtained by Gridnard reaction, when Formaldehyde reacts with Ethyl magnesium lodide?

A

2 - Propanol

B

1 - Propanol

C

Ethanol

D

2 - Methyl, 2 - Propanol

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The correct Answer is:
To determine the product obtained from the Grignard reaction between formaldehyde (HCHO) and ethyl magnesium iodide (C2H5MgI), we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants are formaldehyde (HCHO) and ethyl magnesium iodide (C2H5MgI). 2. **Understand the Grignard Reaction**: - Grignard reagents (like C2H5MgI) are strong nucleophiles. They react with electrophiles, such as carbonyl compounds (like formaldehyde), by attacking the carbon atom of the carbonyl group. 3. **Nucleophilic Attack**: - The ethyl group (C2H5-) from ethyl magnesium iodide will attack the carbonyl carbon of formaldehyde. The carbonyl carbon in formaldehyde is electrophilic due to the partial positive charge it carries. 4. **Formation of Alkoxide Intermediate**: - Upon nucleophilic attack, the carbonyl double bond (C=O) breaks, leading to the formation of an alkoxide intermediate. The structure at this stage can be represented as: \[ CH3CH2 - C(OH) - H \] - Here, the carbon from the ethyl group has bonded to the carbon of formaldehyde, and the oxygen now carries a negative charge. 5. **Protonation**: - The alkoxide intermediate can be protonated by adding water (H2O) in a subsequent step. This results in the formation of an alcohol. - The reaction can be summarized as: \[ CH3CH2 - C(OH) - H \xrightarrow{H2O} CH3CH2 - CH2OH \] 6. **Final Product**: - The final product is 1-propanol (C3H8O), which can be represented as: \[ CH3CH2CH2OH \] ### Conclusion: The product obtained from the Grignard reaction of formaldehyde with ethyl magnesium iodide is **1-propanol**. ---
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