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How many among the following species can...

How many among the following species can be classified as Lewis acids?
`overset(o+)(CH_(3)), Cl^(o+),CO_(2), "CCl"_(2), BCl_(3), BI_(3), Fe^(+2), AlCl_(3)`

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The correct Answer is:
To determine how many of the given species can be classified as Lewis acids, we need to identify which species can accept a lone pair of electrons. A Lewis acid is defined as a substance that can accept an electron pair. Let's analyze each species one by one: 1. **CH₃⁺ (Methyl cation)**: - Carbon in CH₃⁺ has only three hydrogen atoms and a positive charge, indicating it has an empty p-orbital. Thus, it can accept a lone pair of electrons. - **Conclusion**: CH₃⁺ is a Lewis acid. 2. **Cl⁺ (Chloronium ion)**: - Chlorine has 7 valence electrons. In Cl⁺, it loses one electron, leaving it with an empty p-orbital. Therefore, it can accept a lone pair. - **Conclusion**: Cl⁺ is a Lewis acid. 3. **CO₂ (Carbon dioxide)**: - In CO₂, carbon is sp hybridized and has two double bonds with oxygen. The carbon atom can accept a lone pair of electrons due to the presence of empty p-orbitals. - **Conclusion**: CO₂ is a Lewis acid. 4. **CCl₂ (Dichlorocarbene)**: - CCl₂ has two chlorine atoms and a carbon atom with a lone pair of electrons. The carbon atom can accept a lone pair due to its empty p-orbital. - **Conclusion**: CCl₂ can act as a Lewis acid. 5. **BCl₃ (Boron trichloride)**: - Boron has only three valence electrons and forms three bonds with chlorine, leaving it with an empty p-orbital. It can accept a lone pair of electrons. - **Conclusion**: BCl₃ is a Lewis acid. 6. **BI₃ (Boron triiodide)**: - Similar to BCl₃, boron in BI₃ has an empty p-orbital after forming three bonds with iodine. It can accept a lone pair. - **Conclusion**: BI₃ is a Lewis acid. 7. **Fe²⁺ (Iron(II) ion)**: - Iron in the +2 oxidation state has an empty 4s orbital and can accept electron pairs. - **Conclusion**: Fe²⁺ is a Lewis acid. 8. **AlCl₃ (Aluminum chloride)**: - Aluminum in AlCl₃ has an empty p-orbital after forming three bonds with chlorine. It can accept a lone pair of electrons. - **Conclusion**: AlCl₃ is a Lewis acid. Now, let's summarize the findings: - CH₃⁺: Lewis acid - Cl⁺: Lewis acid - CO₂: Lewis acid - CCl₂: Lewis acid - BCl₃: Lewis acid - BI₃: Lewis acid - Fe²⁺: Lewis acid - AlCl₃: Lewis acid **Total count of Lewis acids**: 8 ### Final Answer: **8 species can be classified as Lewis acids.**
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