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In an isothermal expansion of one mole o...

In an isothermal expansion of one mole of an ideal gas against vacuum from 10 litre to 100 litre at `27^(@)C`, the quantity of heat absorbed by the gas is

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To solve the problem of the quantity of heat absorbed by the gas during an isothermal expansion against vacuum, we can follow these steps: ### Step-by-step Solution: 1. **Understand the Process**: - We have an isothermal expansion of one mole of an ideal gas. - The gas expands from a volume of 10 liters to 100 liters at a constant temperature of 27 °C. 2. **Identify Key Concepts**: - **Isothermal Process**: In an isothermal process, the temperature (T) remains constant. Therefore, the change in internal energy (ΔU) for an ideal gas is zero because ΔU = nCvΔT, and ΔT = 0. - **First Law of Thermodynamics**: The first law states that ΔU = Q + W, where Q is the heat absorbed, and W is the work done by the system. 3. **Calculate Change in Internal Energy (ΔU)**: - Since the process is isothermal for an ideal gas, ΔU = 0. 4. **Apply the First Law of Thermodynamics**: - From the first law, we have: \[ ΔU = Q + W \] - Substituting ΔU = 0: \[ 0 = Q + W \] - Rearranging gives: \[ Q = -W \] 5. **Determine Work Done (W)**: - Since the gas is expanding against a vacuum, the external pressure (P_ext) is zero. Thus, the work done by the gas is: \[ W = -P_{ext} \Delta V = -0 \times (V_f - V_i) = 0 \] - Therefore, W = 0. 6. **Calculate Heat Absorbed (Q)**: - Substituting W = 0 into the equation for Q: \[ Q = -W = -0 = 0 \] ### Final Answer: The quantity of heat absorbed by the gas during the isothermal expansion is **0 Joules**.
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