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The incorrect statement about the oxoaci...

The incorrect statement about the oxoacids, `HClO_(4)` and `HClO`, is

A

The central atom in both `HClO_(4)` and `HClO` is `sp^(3)` hybridized

B

`HClO_(4)` is formed in the reaction between `Cl_(2)` and `H_(2)O`

C

The conjugate base of `HClO_(4)` weaker base than `H_(2)O`

D

`HClO_(4)` is more acidic than `HClO` because of the resonance stabilization of its anion

Text Solution

AI Generated Solution

The correct Answer is:
To determine the incorrect statement about the oxoacids \( HClO_4 \) and \( HClO \), we will analyze each statement provided in the context of the properties and structures of these acids. ### Step-by-Step Solution: 1. **Understanding the Hybridization of the Central Atom:** - For \( HClO_4 \): - The structure consists of one chlorine atom (Cl) bonded to four oxygen atoms (O), one of which is connected through a hydroxyl group (OH). - The chlorine atom in \( HClO_4 \) is surrounded by four bond pairs (one single bond to OH and three double bonds to O), and it has no lone pairs. - Therefore, the hybridization of Cl in \( HClO_4 \) is \( sp^3 \). - For \( HClO \): - The structure consists of one chlorine atom bonded to one oxygen atom and one hydrogen atom. - The chlorine atom in \( HClO \) has one bond pair (to O) and three lone pairs. - Therefore, the hybridization of Cl in \( HClO \) is also \( sp^3 \). **Conclusion:** The statement that the central atom in both \( HClO_4 \) and \( HClO \) is \( sp^3 \)-hybridized is **correct**. 2. **Formation of \( HClO_4 \) from \( Cl_2 \) and \( H_2O \):** - The reaction between \( Cl_2 \) and \( H_2O \) typically produces \( HCl \) and \( HOCl \) (hypochlorous acid). - \( HClO_4 \) is not formed in this reaction. **Conclusion:** The statement that \( HClO_4 \) is formed in the reaction between \( Cl_2 \) and \( H_2O \) is **incorrect**. 3. **Conjugate Base Strength of \( HClO_4 \):** - The conjugate base of \( HClO_4 \) is \( ClO_4^- \). - Since \( HClO_4 \) is a strong acid, its conjugate base \( ClO_4^- \) is weak. - Water is a weak acid, and its conjugate base \( OH^- \) is strong. **Conclusion:** The statement that the conjugate base of \( HClO_4 \) is weaker than water is **correct**. 4. **Acidity Comparison of \( HClO_4 \) and \( HClO \):** - \( HClO_4 \) is a stronger acid than \( HClO \) due to the resonance stabilization of its conjugate base \( ClO_4^- \). - In contrast, the conjugate base \( ClO^- \) of \( HClO \) does not have resonance stabilization. **Conclusion:** The statement that \( HClO_4 \) is more acidic than \( HClO \) because of resonance stabilization is **correct**. ### Final Answer: The incorrect statement about the oxoacids \( HClO_4 \) and \( HClO \) is that **\( HClO_4 \) is formed in the reaction between \( Cl_2 \) and \( H_2O \)**.
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