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A monoatomic gas undergoes a process in ...

A monoatomic gas undergoes a process in which the pressure (P) and the volume (V) of the gas are related as `PV^(-3)=`constant. What will be the molar heat capacity of gas for this process?

A

`(5R)/(3)`

B

`(3)/(5)R`

C

`(7)/(5)R`

D

`(R )/(4)`

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The correct Answer is:
To solve the problem, we need to find the molar heat capacity of a monoatomic gas undergoing a process defined by the equation \( PV^{-3} = \text{constant} \). ### Step-by-Step Solution: 1. **Identify the Type of Process**: The given equation \( PV^{-3} = \text{constant} \) can be rewritten as \( PV^n = \text{constant} \) where \( n = -3 \). This indicates that the process is a polytropic process. 2. **Use the Formula for Molar Heat Capacity**: The molar heat capacity \( C \) for a polytropic process can be given by the formula: \[ C = C_v + \frac{R}{1 - n} \] where \( C_v \) is the molar heat capacity at constant volume, \( R \) is the universal gas constant, and \( n \) is the polytropic index. 3. **Determine \( C_v \) for a Monoatomic Gas**: For a monoatomic gas, the molar heat capacity at constant volume \( C_v \) is: \[ C_v = \frac{3R}{2} \] 4. **Substitute Values into the Heat Capacity Formula**: Now, substituting \( C_v \) and \( n \) into the heat capacity formula: \[ C = \frac{3R}{2} + \frac{R}{1 - (-3)} \] Simplifying the denominator: \[ 1 - (-3) = 1 + 3 = 4 \] Thus, the equation becomes: \[ C = \frac{3R}{2} + \frac{R}{4} \] 5. **Find a Common Denominator**: To add these fractions, we need a common denominator. The common denominator between 2 and 4 is 4: \[ C = \frac{6R}{4} + \frac{R}{4} = \frac{6R + R}{4} = \frac{7R}{4} \] 6. **Final Answer**: Therefore, the molar heat capacity of the gas for this process is: \[ C = \frac{7R}{4} \]
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