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The spin only magnetic moment of transit...

The spin only magnetic moment of transition metal ion found to be 5.92 BM. The number of unpaired electrons present in the species is :

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To solve the problem of finding the number of unpaired electrons in a transition metal ion with a spin-only magnetic moment of 5.92 Bohr Magnetons (BM), we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Formula**: The formula for the spin-only magnetic moment (μ_spin) is given by: \[ \mu_{\text{spin}} = \sqrt{n(n + 2)} \] where \( n \) is the number of unpaired electrons. 2. **Substitute the Given Value**: We know that: \[ \mu_{\text{spin}} = 5.92 \, \text{BM} \] Therefore, we can set up the equation: \[ 5.92 = \sqrt{n(n + 2)} \] 3. **Square Both Sides**: To eliminate the square root, we square both sides of the equation: \[ (5.92)^2 = n(n + 2) \] Calculating \( (5.92)^2 \): \[ 5.92^2 = 35.0464 \approx 35.04 \] So we have: \[ 35.04 = n(n + 2) \] 4. **Rearrange the Equation**: Rearranging gives us a quadratic equation: \[ n^2 + 2n - 35.04 = 0 \] For simplicity, we can approximate this to: \[ n^2 + 2n - 35 = 0 \] 5. **Solve the Quadratic Equation**: We can factor or use the quadratic formula to solve for \( n \): \[ n = \frac{-b \pm \sqrt{b^2 - 4ac}}{2a} \] Here, \( a = 1, b = 2, c = -35 \): \[ n = \frac{-2 \pm \sqrt{2^2 - 4 \cdot 1 \cdot (-35)}}{2 \cdot 1} \] \[ n = \frac{-2 \pm \sqrt{4 + 140}}{2} \] \[ n = \frac{-2 \pm \sqrt{144}}{2} \] \[ n = \frac{-2 \pm 12}{2} \] 6. **Calculate Possible Values for n**: This gives us two potential solutions: \[ n = \frac{10}{2} = 5 \quad \text{and} \quad n = \frac{-14}{2} = -7 \] Since the number of unpaired electrons cannot be negative, we take: \[ n = 5 \] 7. **Conclusion**: Therefore, the number of unpaired electrons present in the species is: \[ \boxed{5} \]
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