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Identify X and Y in the following reacti...

Identify X and Y in the following reaction `BCl_(3)+NH_(4)Cl overset(140^(@)C//C_(6)H_(5)Cl)rarr X overset(NaBH_(4))rarr Y`

A

`X=NaBO_(2), Y=B_(2)O_(3)`

B

`X=Na_(2)B_(4)O_(7), Y=H_(3)BO_(3)`

C

`X=BN, Y=[NH_(4)]^(+)[BCl_(4)]^(-)`

D

`X=B_(3)N_(3)H_(3)Cl_(3), Y=B_(3)N_(3)H_(6)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to identify the compounds X and Y in the given reaction sequence. Let's break down the reaction step by step. ### Step 1: Identify the Reaction of BCl₃ with NH₄Cl The first part of the reaction involves the interaction of boron trichloride (BCl₃) with ammonium chloride (NH₄Cl) at a temperature of 140°C in the presence of chlorobenzene (C₆H₅Cl). The reaction can be summarized as: \[ \text{BCl}_3 + \text{NH}_4\text{Cl} \rightarrow \text{B}_3\text{N}_3\text{H}_3\text{Cl}_3 \] This product, B₃N₃H₃Cl₃, is known as borazine, which is often referred to as "inorganic benzene" due to its structural similarity to benzene. ### Step 2: Identify Compound X From the first step, we can conclude that: - **X = B₃N₃H₃Cl₃** ### Step 3: Reduction of X with NaBH₄ Next, we need to reduce compound X (B₃N₃H₃Cl₃) using sodium borohydride (NaBH₄). The reduction process typically involves the replacement of chlorine atoms with hydrogen atoms. The reduction can be summarized as: \[ \text{B}_3\text{N}_3\text{H}_3\text{Cl}_3 + \text{NaBH}_4 \rightarrow \text{B}_3\text{N}_3\text{H}_6 \] This product, B₃N₃H₆, is also borazine but in a fully hydrogenated form, which can be seen as a derivative of borazine. ### Step 4: Identify Compound Y From the reduction step, we find that: - **Y = B₃N₃H₆** ### Final Answer Thus, the identified compounds are: - **X = B₃N₃H₃Cl₃** - **Y = B₃N₃H₆**
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