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When a gas is bubbled through water at 298 K, a very dilute solution of gas is obtained. Henry's law constant for the gas is 100 kbar. If gas exerts a pressure of 1 bar, the number of moles of gas dissolved in 1 litre of water is `x xx 10^(-5)`. Find the value of x here?
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To solve the problem, we will use Henry's law, which states that the amount of gas dissolved in a liquid is directly proportional to the partial pressure of that gas above the liquid. The formula for Henry's law can be expressed as: \[ P = K_H \cdot X_A \] Where: - \( P \) = partial pressure of the gas - \( K_H \) = Henry's law constant - \( X_A \) = mole fraction of the gas in the solution ### Step-by-Step Solution: 1. **Identify Given Values:** - Henry's law constant \( K_H = 100 \, \text{kbar} = 100 \times 10^5 \, \text{Pa} \) (since 1 kbar = \( 10^5 \) Pa) - Partial pressure of the gas \( P = 1 \, \text{bar} = 10^5 \, \text{Pa} \) 2. **Convert Henry's Law Constant to Bar:** - Since \( K_H \) is given in kbar, we convert it to bar: \[ K_H = 100 \, \text{kbar} = 100 \times 10^5 \, \text{Pa} = 100 \, \text{bar} \] 3. **Set Up the Equation Using Henry's Law:** \[ P = K_H \cdot X_A \] Substituting the values we have: \[ 1 \, \text{bar} = 100 \, \text{bar} \cdot X_A \] 4. **Solve for Mole Fraction \( X_A \):** \[ X_A = \frac{1 \, \text{bar}}{100 \, \text{bar}} = 0.01 \] 5. **Calculate Moles of Water in 1 Liter:** - The molarity of water is approximately \( 55.55 \, \text{mol/L} \). 6. **Relate Mole Fraction to Moles:** - The mole fraction \( X_A \) can also be expressed in terms of moles of gas \( n_g \) and moles of water \( n_w \): \[ X_A = \frac{n_g}{n_g + n_w} \] Since \( n_w \) is much larger than \( n_g \) (very dilute solution), we can approximate: \[ X_A \approx \frac{n_g}{n_w} \] 7. **Substituting Values:** - Let \( n_w = 55.55 \, \text{mol} \) (moles of water in 1 liter): \[ 0.01 \approx \frac{n_g}{55.55} \] 8. **Solve for Moles of Gas \( n_g \):** \[ n_g = 0.01 \times 55.55 = 0.5555 \, \text{mol} \] 9. **Express in Scientific Notation:** - The number of moles of gas dissolved in 1 liter of water is: \[ n_g = 0.5555 \, \text{mol} = 55.55 \times 10^{-5} \, \text{mol} \] 10. **Identify the Value of \( x \):** - From the expression \( n_g = x \times 10^{-5} \), we can see that: \[ x = 55.55 \] ### Final Answer: The value of \( x \) is \( 55.55 \).
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