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Complete the missing links CH(3)CHBrCH...

Complete the missing links
`CH_(3)CHBrCH_(3) overset("alc. KOH")rarr Xoverset("HBr, Peroxiden")rarr Y overset(CH_(3)Ona)rarr Z`

A

`{:("X","Y","Z"),(CH_(3)CH=CH_(2),CH_(3)CH(Br)CH_(2)Br,CH_(3)CH(OH)CH_(3)):}`

B

`{:("X","Y","Z"),(CH_(3)CH=CH_(2),CH_(3)CH_(2)CH_(2)Br,CH_(3)CH_(2)OCH_(2)CH_(3)):}`

C

`{:("X","Y","Z"),(CH_(3)CH=CH_(2),CH_(3)CH(Br)CH_(3),CH_(3)CH_(2)OCH_(2)CH_(3)):}`

D

`{:("X","Y","Z"),(CH_(3)CH=CH_(2),CH_(3)CH_(2)CH_(2)Br,CH_(3)CH_(2)CH_(2)OCH_(3)):}`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to identify the missing compounds X, Y, and Z in the given reaction sequence starting from CH₃CHBrCH₃. Let's break it down step by step. ### Step 1: Identify the reaction with alcoholic KOH The first transformation involves the compound CH₃CHBrCH₃ reacting with alcoholic KOH. Alcoholic KOH is a strong base that promotes elimination reactions (dehydrohalogenation). **Reaction:** - CH₃CHBrCH₃ + alc. KOH → CH₃CH=CH₂ + HBr Here, the bromine (Br) is eliminated along with a hydrogen atom (H) from the adjacent carbon, resulting in the formation of an alkene. **Missing Compound X:** - X = CH₃CH=CH₂ (Propene) ### Step 2: Reaction with HBr in the presence of peroxide Next, we take the alkene (X = CH₃CH=CH₂) and react it with HBr in the presence of peroxide. The presence of peroxide leads to an anti-Markovnikov addition of HBr to the alkene. **Reaction:** - CH₃CH=CH₂ + HBr (in presence of peroxide) → CH₃CHBrCH₃ In this case, the bromine (Br) will add to the less substituted carbon atom of the alkene. **Missing Compound Y:** - Y = CH₃CHBrCH₂ (Bromo-propane) ### Step 3: Reaction with CH₃O⁻Na⁺ Finally, we react compound Y (CH₃CHBrCH₂) with sodium methoxide (CH₃O⁻Na⁺). This is a nucleophilic substitution reaction where the methoxide ion (CH₃O⁻) will replace the bromine atom. **Reaction:** - CH₃CHBrCH₂ + CH₃O⁻ → CH₃CH₂CH₂OCH₃ + Br⁻ This results in the formation of an ether. **Missing Compound Z:** - Z = CH₃CH₂CH₂OCH₃ (Methyl propyl ether) ### Summary of the Missing Compounds - X = CH₃CH=CH₂ (Propene) - Y = CH₃CHBrCH₂ (Bromo-propane) - Z = CH₃CH₂CH₂OCH₃ (Methyl propyl ether)
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