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The number of hyperconjugating structure...

The number of hyperconjugating structures shown by the carbocations are given below. Which one is not correctly matched?

A

`CH_(3)-underset(CH_(3))underset("| ")overset(+)"C "-CH_(3)`, 9 hyperconjugating

B

`CH_(3)-overset(+)C-CH_(3)`, 8 hyperconjugating structures

C

`CH_(3)-overset(+)CH_(2)`, 3 hyperconjugating structures

D

`overset(+)CH_(3)`, No hyperconjugating structures

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The correct Answer is:
To solve the question regarding the number of hyperconjugating structures shown by the carbocations, we will analyze each option provided and determine which one is incorrectly matched. ### Step-by-Step Solution: 1. **Understanding Hyperconjugation**: - Hyperconjugation is the interaction between the electrons in a σ-bond (usually C-H or C-C) and an adjacent empty or partially filled p-orbital. This interaction stabilizes the carbocation. 2. **Identifying Carbocations**: - We need to identify the carbocations in each option and count the number of hyperconjugating structures they can exhibit. 3. **Counting Hyperconjugating Structures**: - For each carbocation, we will count the number of adjacent carbon atoms that can donate σ-bonds to the empty p-orbital of the carbocation. 4. **Analyzing Each Option**: - **Option 1**: If the carbocation has 3 adjacent carbons, the number of hyperconjugating structures is 3 (from each adjacent carbon) × 3 (the number of hydrogens on each adjacent carbon) = 9. - **Option 2**: If the carbocation has 2 adjacent carbons, the number of hyperconjugating structures is 2 × 3 = 6. (This option is incorrectly matched if it states 8). - **Option 3**: If the carbocation has 1 adjacent carbon, the number of hyperconjugating structures is 1 × 3 = 3. - **Option 4**: If the carbocation has 3 adjacent carbons again, the number of hyperconjugating structures is 3 × 3 = 9. 5. **Conclusion**: - After analyzing all options, we find that **Option 2** is the one that is not correctly matched, as it states 8 instead of the correct 6 hyperconjugating structures. ### Final Answer: The option that is not correctly matched is **Option 2**.
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