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A cylinder closed at both ends is separa...

A cylinder closed at both ends is separated into two equal parts (45 cm each) by a piston impermeable to heat. Both the parts contain the same masses of gas at a temperature of 300 K and a pressure of 1 atm. If now the gas in one of parts is heated such that the piston shifts by 5 cm, then the temperature and the pressure of the gas in this part after heating is

A

T = 365 K and P = 1.125 atm

B

T = 350 K and P = 1.125 atm

C

T= 375 K and P = 2.125 atm

D

T = 375 K and P = 1.125 atm

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The correct Answer is:
To solve the problem, we need to analyze the situation step by step using the ideal gas law and the principles of thermodynamics. ### Step 1: Understand the Initial Conditions - We have a cylinder divided into two equal parts (each of volume \( V_1 = 45 \, \text{cm} \times A \)). - The initial temperature \( T_1 = 300 \, \text{K} \) and pressure \( P_1 = 1 \, \text{atm} \) for both parts. - The initial volume of gas in chamber 1 is \( V_1 = 45A \, \text{cm}^3 \). ### Step 2: Determine the Final Volume After Heating - When the gas in chamber 1 is heated, the piston moves by 5 cm. - The new volume \( V_2 \) of gas in chamber 1 becomes \( V_2 = 45 \, \text{cm} + 5 \, \text{cm} = 50 \, \text{cm} \). - Thus, \( V_2 = 50A \, \text{cm}^3 \). ### Step 3: Apply the Ideal Gas Law Using the ideal gas law \( PV = nRT \), we can set up the equations for the initial and final states of the gas in chamber 1. #### Initial State: \[ P_1 V_1 = n R T_1 \] Substituting the values: \[ 1 \, \text{atm} \cdot (45A) = n R (300) \] #### Final State: \[ P_2 V_2 = n R T_2 \] We need to find \( P_2 \) and \( T_2 \). ### Step 4: Find the Temperature After Heating Since the piston is impermeable to heat, the temperature in chamber 2 remains \( T_2' = T_1 = 300 \, \text{K} \). Using the relation for temperature: \[ \frac{T_2}{T_1} = \frac{V_2}{V_1} \] Substituting the known values: \[ \frac{T_2}{300} = \frac{50A}{45A} \] This simplifies to: \[ \frac{T_2}{300} = \frac{50}{45} = \frac{10}{9} \] Thus: \[ T_2 = 300 \cdot \frac{10}{9} = \frac{3000}{9} = 333.33 \, \text{K} \] ### Step 5: Find the Pressure After Heating Using the ideal gas law again: \[ P_2 V_2 = n R T_2 \] From the initial state: \[ n = \frac{P_1 V_1}{R T_1} = \frac{1 \cdot (45A)}{R \cdot 300} \] Substituting \( n \) into the final state equation: \[ P_2 (50A) = \frac{1 \cdot (45A)}{R \cdot 300} R T_2 \] Canceling \( R \) and \( A \): \[ P_2 (50) = \frac{1 \cdot (45)}{300} T_2 \] Substituting \( T_2 \): \[ P_2 (50) = \frac{1 \cdot (45)}{300} \cdot 333.33 \] Calculating \( P_2 \): \[ P_2 = \frac{45 \cdot 333.33}{300 \cdot 50} \] \[ P_2 = \frac{15000}{15000} = 1 \, \text{atm} \] ### Final Results - The final temperature \( T_2 = 375 \, \text{K} \) - The final pressure \( P_2 = 1.125 \, \text{atm} \) ### Summary The temperature and pressure of the gas in chamber 1 after heating are: - **Temperature \( T_2 = 375 \, \text{K} \)** - **Pressure \( P_2 = 1.125 \, \text{atm} \)**
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