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The ions present in Al(4)C(3), CaC(2) an...

The ions present in `Al_(4)C_(3), CaC_(2)` and `Mg_(2)C_(3)` are respectively

A

`C^(4-), C_(2)^(2-), C_(3)^(4-)`

B

`C_(2)^(2-), C^(4-), C_(3)^(4-)`

C

`C_(2)^(2-), C_(3)^(2-), C^(4-)`

D

`C_(3)^(4-), C^(4-), C_(2)^(2-)`

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The correct Answer is:
To determine the ions present in the compounds \( \text{Al}_4\text{C}_3 \), \( \text{CaC}_2 \), and \( \text{Mg}_2\text{C}_3 \), we will analyze each compound step by step. ### Step 1: Analyze \( \text{Al}_4\text{C}_3 \) 1. **Identify the oxidation state of Aluminum (Al)**: - Aluminum typically has an oxidation state of +3. - In \( \text{Al}_4\text{C}_3 \), there are 4 Aluminum atoms, contributing a total charge of \( 4 \times (+3) = +12 \). 2. **Determine the charge contributed by Carbon (C)**: - The compound must be electrically neutral, so the total negative charge from Carbon must balance the +12 charge from Aluminum. - Let the charge on Carbon be \( x \). Since there are 3 Carbon atoms, the total charge from Carbon is \( 3x \). - Therefore, we set up the equation: \[ +12 + 3x = 0 \] - Solving for \( x \): \[ 3x = -12 \quad \Rightarrow \quad x = -4 \] - Thus, the ion present is \( \text{C}^{4-} \). ### Step 2: Analyze \( \text{CaC}_2 \) 1. **Identify the oxidation state of Calcium (Ca)**: - Calcium typically has an oxidation state of +2. - In \( \text{CaC}_2 \), there is 1 Calcium atom contributing a total charge of +2. 2. **Determine the charge contributed by Carbon (C)**: - Let the charge on Carbon be \( y \). Since there are 2 Carbon atoms, the total charge from Carbon is \( 2y \). - The compound must be electrically neutral, so we set up the equation: \[ +2 + 2y = 0 \] - Solving for \( y \): \[ 2y = -2 \quad \Rightarrow \quad y = -1 \] - Thus, the ion present is \( \text{C}^{2-} \). ### Step 3: Analyze \( \text{Mg}_2\text{C}_3 \) 1. **Identify the oxidation state of Magnesium (Mg)**: - Magnesium typically has an oxidation state of +2. - In \( \text{Mg}_2\text{C}_3 \), there are 2 Magnesium atoms contributing a total charge of \( 2 \times (+2) = +4 \). 2. **Determine the charge contributed by Carbon (C)**: - Let the charge on Carbon be \( z \). Since there are 3 Carbon atoms, the total charge from Carbon is \( 3z \). - The compound must be electrically neutral, so we set up the equation: \[ +4 + 3z = 0 \] - Solving for \( z \): \[ 3z = -4 \quad \Rightarrow \quad z = -\frac{4}{3} \] - Thus, the ion present is \( \text{C}^{4-} \). ### Summary of Ions Present - For \( \text{Al}_4\text{C}_3 \): \( \text{C}^{4-} \) - For \( \text{CaC}_2 \): \( \text{C}^{2-} \) - For \( \text{Mg}_2\text{C}_3 \): \( \text{C}^{4-} \) ### Final Answer The ions present in \( \text{Al}_4\text{C}_3 \), \( \text{CaC}_2 \), and \( \text{Mg}_2\text{C}_3 \) are \( \text{C}^{4-} \), \( \text{C}^{2-} \), and \( \text{C}^{4-} \) respectively. ---
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