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Which of the following organic compounds...

Which of the following organic compounds has same hybridization as its combustion product `(CO_(2))`?

A

Ethanol

B

Ethyne

C

Ethene

D

Ethane

Text Solution

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The correct Answer is:
To determine which organic compound has the same hybridization as its combustion product \( CO_2 \), we need to analyze the hybridization of \( CO_2 \) and compare it with the hybridization of the given organic compounds. ### Step-by-Step Solution: 1. **Identify the Hybridization of \( CO_2 \)**: - The central atom in \( CO_2 \) is carbon (C). - Carbon has 4 valence electrons. - The formula for calculating hybridization is: \[ \text{Hybridization} = \frac{1}{2} \left( \text{Number of valence electrons on central atom} + \text{Number of monovalent atoms} + \text{Charge} \right) \] - For \( CO_2 \): - Valence electrons on carbon = 4 - Number of monovalent atoms = 0 (no hydrogen or other monovalent atoms directly bonded to carbon) - Charge = 0 - Plugging in the values: \[ \text{Hybridization} = \frac{1}{2} (4 + 0 + 0) = \frac{4}{2} = 2 \] - A hybridization value of 2 corresponds to \( sp \) hybridization. 2. **Analyze the Given Organic Compounds**: - We need to find which of the following compounds has \( sp \) hybridization: 1. Ethanol (\( C_2H_5OH \)) 2. Ethyne (\( C_2H_2 \)) 3. Ethene (\( C_2H_4 \)) 4. Ethane (\( C_2H_6 \)) 3. **Determine the Hybridization of Each Compound**: - **Ethanol (\( C_2H_5OH \))**: - Structure: \( C_2H_5OH \) has all single bonds. - Hybridization: Each carbon is \( sp^3 \). - **Ethyne (\( C_2H_2 \))**: - Structure: \( C \equiv C \) (triple bond between two carbons). - Hybridization: Each carbon is \( sp \) (one triple bond). - **Ethene (\( C_2H_4 \))**: - Structure: \( C=C \) (double bond between two carbons). - Hybridization: Each carbon is \( sp^2 \). - **Ethane (\( C_2H_6 \))**: - Structure: All single bonds. - Hybridization: Each carbon is \( sp^3 \). 4. **Conclusion**: - The only compound that has \( sp \) hybridization, like \( CO_2 \), is **Ethyne (\( C_2H_2 \))**. ### Final Answer: Ethyne (\( C_2H_2 \)) has the same hybridization as its combustion product \( CO_2 \).
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