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The ratio of acid strength of HOCN and H...

The ratio of acid strength of `HOCN` and `HCN` is about
Given `K_(a)` of `HOCN=1.2xx10^(-4) and K_(a)" of "HCN "=4.2 xx10^(-10)`

A

`535:1`

B

`1:535`

C

`2.86xx10^(5):1`

D

`2.86xx10^(4):1`

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The correct Answer is:
To find the ratio of the acid strength of HOCN and HCN, we will use the given acid dissociation constants \( K_a \) for both acids. ### Step-by-Step Solution: 1. **Identify the given values:** - \( K_a \) for HOCN = \( 1.2 \times 10^{-4} \) - \( K_a \) for HCN = \( 4.2 \times 10^{-10} \) 2. **Understand the relationship between \( K_a \) and acid strength:** - The strength of an acid is directly related to its \( K_a \) value. A higher \( K_a \) indicates a stronger acid because it means that the acid dissociates more in solution, producing more \( H^+ \) ions. 3. **Set up the ratio of acid strengths:** - The ratio of the acid strengths can be expressed as: \[ \text{Ratio} = \sqrt{\frac{K_{a \text{ (HOCN)}}}{K_{a \text{ (HCN)}}}} \] 4. **Substitute the values into the equation:** \[ \text{Ratio} = \sqrt{\frac{1.2 \times 10^{-4}}{4.2 \times 10^{-10}}} \] 5. **Calculate the fraction inside the square root:** - First, calculate the fraction: \[ \frac{1.2 \times 10^{-4}}{4.2 \times 10^{-10}} = \frac{1.2}{4.2} \times 10^{6} \approx 0.2857 \times 10^{6} \] - This simplifies to: \[ 2.857 \times 10^{5} \] 6. **Take the square root:** \[ \text{Ratio} = \sqrt{2.857 \times 10^{5}} \approx 534 \] 7. **Final Result:** - The ratio of the acid strength of HOCN to HCN is approximately \( 534:1 \).
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