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Ph-CH2-C-=CHunderset(Y)overset(X)hArrPh-...

`Ph-CH_2-C-=CHunderset(Y)overset(X)hArrPh-C-=C-CH_3`.
The reagents X and Y respectively are

A

Lindlar catalyst , `NaNH_2`

B

`NaNH_2` and alc . KOH

C

Pt catalyst , Wilkison's catalyst

D

Alc. KOH and `NaNH_2`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to identify the reagents X and Y that facilitate the transformation of the given organic compounds. ### Step-by-Step Solution: 1. **Identify the Reactants and Products:** - The starting compound is a terminal alkyne: Ph-CH₂-C≡CH (where Ph represents a phenyl group). - The product is an internal alkyne: Ph-C≡C-CH₃. 2. **Determine Reagent Y:** - To convert a terminal alkyne to an internal alkyne, we typically need a reagent that can abstract a proton and form a carbon anion. - In this case, the reagent Y is **sodium amide (NaNH₂)**. Sodium amide will abstract the proton from the terminal alkyne, resulting in the formation of a carbon anion, which can then undergo tautomerization to form the internal alkyne. 3. **Determine Reagent X:** - To convert the internal alkyne back to a terminal alkyne, we need a reagent that can add a proton to the carbon anion formed from the internal alkyne. - The reagent X is **alcoholic KOH (potassium hydroxide in alcohol)**. This reagent will abstract a proton from the terminal alkyne, leading to the formation of the internal alkyne. 4. **Final Answer:** - Therefore, the reagents X and Y are: - X = Alcoholic KOH - Y = Sodium Amide (NaNH₂) ### Summary: - The reagents X and Y respectively are: - X = Alcoholic KOH - Y = Sodium Amide (NaNH₂)
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