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Which of the following is the correct or...

Which of the following is the correct order of radius ?

A

`H^(-)gtHgtH^+`

B

`Na^(+) gtF^(-)gtO^(2-)`

C

`F^(-) gtO^(2-)gt Na^+`

D

`Al^(3+)gtMg^(2+)gtN^(3-)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct order of radius for the given species, we will analyze the ions and their electron configurations step by step. ### Step 1: Analyze H-, H, and H+ - **H- (Hydride Ion)**: Contains 2 electrons and 1 proton. The presence of an extra electron increases the electron-electron repulsion, leading to a larger radius. - **H (Neutral Hydrogen Atom)**: Contains 1 electron and 1 proton. It has a smaller radius compared to H- because it has less electron-electron repulsion. - **H+ (Hydrogen Ion)**: Contains no electrons and only 1 proton. This results in a very small radius since there are no electrons to repel each other. **Order of radius**: H- > H > H+ ### Step 2: Analyze Na+, F-, and O2- - **Na+ (Sodium Ion)**: Contains 10 electrons (after losing one electron) and has 11 protons. The effective nuclear charge is relatively high, pulling the electrons closer. - **F- (Fluoride Ion)**: Contains 10 electrons (after gaining one electron) and has 9 protons. The lower nuclear charge compared to Na+ means that the electrons are held less tightly, resulting in a larger radius. - **O2- (Oxide Ion)**: Contains 10 electrons (after gaining two electrons) and has 8 protons. With the least nuclear charge, the electrons are held the least tightly, leading to the largest radius. **Order of radius**: O2- > F- > Na+ ### Step 3: Analyze Al3+, Mg2+, and Ne - **Al3+ (Aluminum Ion)**: Contains 10 electrons and has 13 protons. The high nuclear charge pulls the electrons very close, resulting in a small radius. - **Mg2+ (Magnesium Ion)**: Contains 10 electrons and has 12 protons. The nuclear charge is less than that of Al3+, resulting in a larger radius than Al3+. - **Ne (Neon)**: Contains 10 electrons and has 10 protons. The nuclear charge is lower than that of Al3+ and Mg2+, giving it a larger radius than Al3+ but smaller than Mg2+. **Order of radius**: Al3+ < Mg2+ < Ne ### Final Summary of Radius Orders 1. **For H-, H, H+**: H- > H > H+ 2. **For Na+, F-, O2-**: O2- > F- > Na+ 3. **For Al3+, Mg2+, Ne**: Al3+ < Mg2+ < Ne
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