Home
Class 12
CHEMISTRY
PhMgBr+underset((2)H^(o+))overset((1)X)r...

`PhMgBr+underset((2)H^(o+))overset((1)X)rarrPh-underset(Ph)underset(|)overset(OH)overset(|)C-Ph`
X is

A

`Ph-overset(O)overset(||)C-H`

B

`Ph-overset(O)overset(||)C-Ph`

C

`Ph-underset(Ph)underset(|)(CH)-overset(O)overset(||)C-H`

D

`Ph-overset(O)overset(||)C-CH_3`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to identify the compound X that reacts with PhMgBr and produces the specified product after the addition of H⁺. Let's break down the steps: ### Step 1: Understanding the Reactants - We have PhMgBr, which is a Grignard reagent. Grignard reagents are strong nucleophiles and will react with electrophiles. - The question indicates that we will react PhMgBr with a compound X, followed by the addition of H⁺. ### Step 2: Analyzing the Product - The product is given as Ph-Ph-CH(OH)-Ph, which indicates that we have a tertiary alcohol with three phenyl (Ph) groups attached to a carbon that also has a hydroxyl (OH) group. ### Step 3: Identifying Possible Candidates for X - We need to determine which of the four options can serve as X to produce the desired product. - The compound X must have a carbonyl (C=O) group since Grignard reagents typically react with carbonyl compounds to form alcohols. ### Step 4: Testing Each Option 1. **Option 1**: If we assume X is PhCHO (benzaldehyde), the reaction would yield: - PhMgBr attacks the carbonyl carbon, leading to the formation of a compound with a negative charge on oxygen. - After protonation, we would get Ph-CH(OH)-Ph, which is not the desired product. 2. **Option 2**: If X is PhCOPh (benzophenone), the reaction would yield: - PhMgBr attacks the carbonyl carbon of PhCOPh, forming a compound with a negative charge on oxygen. - After protonation, we would get Ph-CH(OH)-Ph, which matches the desired product. 3. **Option 3**: If X is PhC(OH)Ph, the reaction would not yield the desired product as it already contains an alcohol group. 4. **Option 4**: If X is PhC(O)CH₃ (acetophenone), the reaction would yield: - PhMgBr attacks the carbonyl carbon, leading to a compound that does not match the desired product. ### Step 5: Conclusion - Based on the analysis, **Option 2 (PhCOPh)** is the correct choice for X, as it leads to the formation of the desired product after the reaction with PhMgBr and subsequent protonation. ### Final Answer **X is PhCOPh (benzophenone).** ---
Promotional Banner

Topper's Solved these Questions

  • NTA NEET SET 54

    NTA MOCK TESTS|Exercise CHEMISTRY|45 Videos
  • NTA NEET SET 56

    NTA MOCK TESTS|Exercise CHEMISTRY|45 Videos

Similar Questions

Explore conceptually related problems

CH_(3) - underset(H) underset(|)overset(OH)overset(|)(C ) - CN is

Ph - underset(OH) underset(|)overset(CH_(3))overset(|)(C) - underset(OH) underset(|)overset(Ph)overset(|)(C) - Ph underset(H_(2)SO_(4))overset("Conc")rarr Product is

Cl-underset(Cl)underset(|)overset(Cl)overset(|)(C)-underset(H)underset(|)overset(OH)overset(|)(C)-OH

Ph-underset(OH)underset(|)overset(Ph)overset(|)C-underset(OH)underset(|)overset(CH_(3))overset(|)C-CH_(3)+Ph-underset(OH)underset(|)overset(Ph)overset(|)C-underset(OH)underset(|)overset(Et)overset(|)C-Et overset(H_(2)SO_(4))to

Ph-underset(OH)underset(|)overset(Ph)overset(|)(C)-underset(OH)underset(|)overset(H)overset(|)(C)-overset(HTheta)(rarr)underset("Major")(X) identify X.

Identify and name the functional groups present in the following compounds. (a) H-underset(H)underset(|)overset(H)overset(|)C-underset(H)underset(|)overset(H)overset(|)C-underset(H)underset(|)overset(H)overset(|)C-OH , (b) H-underset(H)underset(|)overset(H)overset(|)C-underset(H)underset(|)overset(H)overset(|)C-overset(O)overset(||)C-OH (c ) H-underset(H)underset(|)overset(H)overset(|)C-underset(H)underset(|)overset(H)overset(|)C-overset(O)overset(||)C-underset(H)underset(|)overset(H)overset(|)C-underset(H)underset(|)overset(H)overset(|)C-H , (d) H-underset(H)underset(|)overset(H)overset(|)C-underset(H)underset(|)overset(H)overset(|)C-overset(H)overset(|)C=overset(H)overset(|)C-H

NTA MOCK TESTS-NTA NEET SET 55-CHEMISTRY
  1. What is the density of solution of sulphuric acid used as an electroly...

    Text Solution

    |

  2. Name the common elements present in the anode mud in the eletrolytic r...

    Text Solution

    |

  3. PhMgBr+underset((2)H^(o+))overset((1)X)rarrPh-underset(Ph)underset(|)o...

    Text Solution

    |

  4. Pick out the correct statement with respect to [Mn(CN)(6)]^(3-):

    Text Solution

    |

  5. The increasing order of atomic radii of the following Group 13 element...

    Text Solution

    |

  6. Identify the monosaccharide containing only one asymmetric carbon atom...

    Text Solution

    |

  7. Which of the following compounds is (S) - 4 - chloro - 1- methylcycloh...

    Text Solution

    |

  8. When equal volume of the following solutions are mixed , which of the ...

    Text Solution

    |

  9. The correct order of increasing bond angle in the following species is

    Text Solution

    |

  10. The maximum prescribed concentration of cadmium in drinking water in p...

    Text Solution

    |

  11. The reactant 'P' in the following reactions is P underset(dil.H2SO4)ov...

    Text Solution

    |

  12. The maximum number of 90^(@) angles between bond pair-bond pair of ele...

    Text Solution

    |

  13. Calculate the energy in joule corresponding to light of wavelength 45 ...

    Text Solution

    |

  14. 1.0 g of Mg is burnt with 0.28 g of O2 in a closed vessel . Which reac...

    Text Solution

    |

  15. Which of the following carboxylic acids is a tricarboxylic acid?

    Text Solution

    |

  16. Metal carbides on reaction with H2O form CH4 , Carbide can be

    Text Solution

    |

  17. Which of the following carbocations is most stable ?

    Text Solution

    |

  18. Calculate the wok done during combustion of 0.138 kg of ethanol, C2 H5...

    Text Solution

    |

  19. When SO2 gas is passed into aqueous Na2CO3 , the product (s) formed is...

    Text Solution

    |

  20. The correct match between items of List - I and List - II is

    Text Solution

    |