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For the reation given below, identify X ...

For the reation given below, identify X in the reaction
`CH_3C -= CCH_3 overset(X)rarr CH_3COCOCH_3`

A

`K_2Cr_2O_7//H_2SO_4`

B

`O_2`

C

`O_3, Zn//H_2O`

D

`HNO_3`

Text Solution

AI Generated Solution

The correct Answer is:
To identify the reagent X in the reaction \[ CH_3C \equiv CCH_3 \overset{X}{\rightarrow} CH_3COCOCH_3 \] we need to analyze the transformation taking place in the reaction. ### Step 1: Identify the starting material and product The starting material is 2-butyne (CH₃C≡CCH₃), which is an alkyne. The product is 3-pentanone (CH₃COCOCH₃), which contains a carbonyl group (C=O) and suggests that some form of oxidation or cleavage is occurring. **Hint:** Look for a reagent that can cleave the triple bond and introduce carbonyl groups. ### Step 2: Understand the reaction type The reaction involves the conversion of an alkyne to a compound with carbonyl groups. This suggests that we are dealing with ozonolysis, a reaction where ozone (O₃) is used to cleave double or triple bonds. **Hint:** Recall that ozonolysis is commonly used for alkenes and alkynes to produce carbonyl compounds. ### Step 3: Write the ozonolysis reaction In ozonolysis, the alkyne reacts with ozone (O₃) to form an intermediate that can rearrange and subsequently be reduced. The typical reducing agents used after ozonolysis are zinc (Zn) and water (H₂O). **Hint:** Remember that after ozonolysis, a reducing agent is often required to convert the ozonide into carbonyl compounds. ### Step 4: Combine the reagents Thus, the reagent X that facilitates this transformation is a combination of ozone (O₃) followed by zinc (Zn) in the presence of water (H₂O). **Hint:** Think about the sequence of ozonolysis followed by reduction when identifying the reagents. ### Conclusion The correct identification of X in the reaction is: \[ X = O_3 \text{ (ozone) and Zn/H₂O} \] This means the complete reaction can be summarized as: \[ CH_3C \equiv CCH_3 \overset{O_3, Zn/H_2O}{\rightarrow} CH_3COCOCH_3 \] ### Final Answer X is O₃ (ozone) followed by Zn and H₂O. ---
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