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M(OH)x has a K(sp) or 4xx10^(-9) and it...

`M(OH)_x` has a `K_(sp)` or `4xx10^(-9)` and its is solubility is `10^(-3)` M. The value of x is

A

4

B

1

C

3

D

2

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The correct Answer is:
To solve the problem, we need to determine the value of \( x \) in the compound \( M(OH)_x \) given its solubility and \( K_{sp} \). ### Step-by-Step Solution: 1. **Understanding the Dissociation:** The compound \( M(OH)_x \) dissociates in water as follows: \[ M(OH)_x \rightleftharpoons M^x + xOH^- \] Here, \( M \) is the metal cation and \( OH^- \) is the hydroxide ion. 2. **Setting Up the Solubility:** Let the solubility of \( M(OH)_x \) be \( S = 10^{-3} \) M. When it dissolves, it produces \( x \) moles of \( OH^- \) ions for every mole of \( M(OH)_x \) that dissolves. Therefore, the concentration of \( M^x \) will be \( S \) and the concentration of \( OH^- \) will be \( xS \). 3. **Expressing \( K_{sp} \):** The solubility product constant \( K_{sp} \) is given by: \[ K_{sp} = [M^x][OH^-]^x \] Substituting the concentrations: \[ K_{sp} = S \cdot (xS)^x \] This simplifies to: \[ K_{sp} = S \cdot x^x \cdot S^x = S^{x+1} \cdot x^x \] 4. **Substituting Known Values:** Given \( K_{sp} = 4 \times 10^{-9} \) and \( S = 10^{-3} \): \[ 4 \times 10^{-9} = (10^{-3})^{x+1} \cdot x^x \] 5. **Simplifying the Equation:** \[ 4 \times 10^{-9} = 10^{-3(x+1)} \cdot x^x \] To isolate \( x^x \), we can express \( 10^{-9} \) as \( 10^{-3(x+1)} \): \[ 10^{-3(x+1)} = 4 \times 10^{-9} \] This gives us: \[ -3(x+1) = -9 \implies 3(x+1) = 9 \implies x + 1 = 3 \implies x = 2 \] 6. **Final Verification:** We can verify by substituting \( x = 2 \) back into the equation: \[ K_{sp} = (10^{-3})^{2+1} \cdot 2^2 = (10^{-3})^3 \cdot 4 = 10^{-9} \cdot 4 = 4 \times 10^{-9} \] This confirms our solution is correct. ### Conclusion: The value of \( x \) is \( 2 \).
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