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Which of the following is least stable...

Which of the following is least stable

A

`BeH_2`

B

`MgH_2`

C

`CaH_2`

D

`BaH_2`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given hydrides is the least stable, we can follow these steps: ### Step 1: Identify the Group The question refers to hydrides of alkaline earth metals, which include beryllium (Be), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), and radium (Ra). The hydrides in question are BeH₂, MgH₂, CaH₂, and BaH₂. **Hint:** Remember that alkaline earth metals have two valence electrons, which influences the stability of their hydrides. ### Step 2: Understand Stability Trends As we move down the group from beryllium to barium, the size of the central atom increases. This increase in atomic size leads to a decrease in electronegativity, which affects the strength of the bond between the metal and hydrogen. **Hint:** Consider how atomic size and electronegativity influence bond strength. ### Step 3: Analyze Bond Strength The bond strength between the metal and hydrogen decreases as the size of the metal atom increases. This means that the bonds in the hydrides become weaker as we go down the group. Weaker bonds are more likely to break, leading to lower stability. **Hint:** Think about how bond strength relates to stability; weaker bonds mean less stability. ### Step 4: Compare the Hydrides Now we can compare the stability of the given hydrides: - BeH₂ (Beryllium Hydride) - Stronger bond due to smaller size and higher electronegativity. - MgH₂ (Magnesium Hydride) - Weaker than BeH₂ but still relatively stable. - CaH₂ (Calcium Hydride) - Weaker than MgH₂. - BaH₂ (Barium Hydride) - The weakest bond due to the largest size and lowest electronegativity. **Hint:** Look for the hydride with the largest central atom for the least stability. ### Step 5: Conclusion Based on the analysis, BaH₂ (Barium Hydride) is the least stable hydride among the given options due to the weakest bond formed with hydrogen. **Final Answer:** BaH₂ is the least stable hydride.
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