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A neutral organic compound X of molecual...

A neutral organic compound X of molecualr formula `C_(2)H_(6)O` on oxidation with acidified potassium dichromate gives an acidic compound Y. Compound X reacts with Y on warming in the presence of conc `H_(2)SO_(4)` to give a sweet smelling substance Z.What are X,Y and Z?

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The correct Answer is:
X is ethanol ; Y is ethanoic acid ;Z is ethyl ethanoate
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Ethanol when warmed with ethanoic acid in the presence of conc,. H_(2)SO_(4) produces a sweet - smelling substance.

An organic compound of molecular formula C_(2)H_(6)O when oxidized with alkaline KmnO_(4) solution and then treated with dilute hydrochloric acid gives a compound A. When A is warmed with ehtanol in the presence of conc .H_(2)SO_(4) it forms the compound B. B when reacted with NaOH solution gives a compound C. (i) Give the names of A, B and C. (ii) Give equations for the above reactions.

An alcohol [A] with molecules formula (C_(4)H_(10)O) o oxidation with aciddified potassium dichromate gives acid [B] (C_(4)H_(8)O_(2)) . Compound [A] when dehydrated with conc. H_(2)SO_(4) at 443 K gives compound [C]. Treatment of [C] with aqueous H_(2)SO_(4) gives compound [D] (C_(4)H_(10)O) which is an isomer of [A]. compound [D] is resistant to oxidation but compound [A]can be easily oxidised. Identify [A], [B], [C] and [D]. Name the type of isomerism exhibited by [A] and [D].

A neutral organic compound A of molecular formula C_(2)H_(6)O on heating with excess of conc. H_(2)SO_(4) gives compound B of molecular formula C_(2)H_(4) . Compound B on reduction gives compound C of molecular formula C_(2)H_(6) . (a) Name A, B and C. (b) Write chemical equation for the conversion of A to B. (c) What is the role of conc H_(2)SO_(4) in the above equation.

LAKHMIR SINGH & MANJIT KAUR-CARBON AND ITS COMPOUNDS-Exercise
  1. The usual disease caused by the excessive drinking of alcohol over a l...

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  2. Which of the following molecular formula corresponds to ethyl butanoat...

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  3. A neutral organic compound X of molecualr formula C(2)H(6)O on oxidati...

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  4. Consider the following organic cpompounds: HCHO,C(2)H(5)OH,C(2)H(6),...

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  5. A neutral organic compound is warmed with some ethanoic acid and a lit...

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  6. The structrual formula of an ester is : Write the formula of the ...

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  7. Consider the following organci compounds: CH(3)OH,C(2)H(5)OH,CH(3)CO...

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  8. An organic acid X is a liquid , which of ten freezes during winter tim...

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  9. An organic compoud A having the molecualr formufla C(3)H(8)O is a liqu...

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  10. A compound C (molecular formula, C(2)H(4)O(2)) reacts with Na metal to...

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  11. Which of the following hydrocarbons can decolourise bromine water and ...

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  12. A four carbon atoms containing neutral oranic compoud X reacts with so...

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  13. What would be the electron dot structure of carbon dioxide which has t...

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  14. What would be the electron dot structure of a molecule of sulphur whic...

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  15. How many structural isomers can you draw for pentane?

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  16. What are the two properties of carbon which lead to the huge number of...

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  17. What will be the formula and electron dot structure of cyclopentane?

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  18. Draw the structures for the following compounds. (i) Ethanoic acid ,...

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  19. How would you name the following compounds? (i) CH(3)-CH(2)-Br , (ii...

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  20. Why is the conversion of ethanol to ethanoic acid an oxidation reactio...

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