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When 1.88 g of AgBr(s) is added to a 10^...

When `1.88 g` of AgBr(s) is added to a `10^(-3)` M aqueous solution of KBr, the concentrationof Ag is `5xx10^(-10)`M. If the same amout of AgBr(s) is added to a `10^(-2)` M aqueous solution of `AgNO_(3)`, the concentration of `Br^(-)` is

A

`9.4xx10^(-9)M`

B

`5xx10^(-10)M`

C

`1xx10^(-11)M`

D

`5xx10^(-11)M`

Text Solution

Verified by Experts

The correct Answer is:
D

`K_(sp(AgBr))=[Ag^(+)][Br^(-)]`
`=(5xx10^(-10))(10^(-3))`
`=5xx10^(-13)`
Now
`5xx10^(-13)=(10^(-2))[Br]`
`[Br^(-)]=5xx10^(-11)M`
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