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The geometry and the number of unpaired ...

The geometry and the number of unpaired electron (s) of `["MnBr"_(4)]^(2-)`, respectively, are

A

tetrahedral and 1

B

square planar and 1

C

tetrahedral and 5

D

square planar and 5

Text Solution

Verified by Experts

The correct Answer is:
C

`["Mn Br"_(4)]^(-2)`
`x+(-1)4=-2`
`x=+2`
`Mn to 4s^(2)3d^(5)`
`Mn^(+2) to 4s^(@)3d^(5)`

We know that Br is weak field ligand so Hund's Rule is applicable

Hybridization is ` to sp^(3)`
and `N_(0)` of unpaired =5
electron.
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