KOLBE'S ELECTROLYSIS

KOLBE'S SYNTHESIS

Kolbe Electrolysis for Alkene Preperation|| Examples OF Anti MarkownikOFf Addition Reaction or Peroxide Effect or Kharasch Effect||Application OF NBS (N-Bromo Succinamide)||NCS ( N-Chloro Succinamide)

{:(CH_2-CO_2 K ),(|),(CH_2 -CO_2 K):} overset("electrolysis ") to underset(("major"))((A)) (Kolbe electrolysis method) Product (A) of the reaction is :

An organic compound A(C_4 H_7 C_(13)) yields (B) when treated with aq. KOH. (B) upon treatment with C_2 H_5 OH in presence of acid gave (C) which upon reducing with LiAIH_4 gave (D) and (E). (B) upon treatment with NH_3 followed by heating with P_4 O_(10) and subsequent hydrolysis gives back (B). Sodium salt of (B) on Kolbe's electrolysis gave 2, 3-dimethylbutane at anode. The IUPAC name of compound (A) is

An organic compound A(C_4 H_7 C_(13)) yields(B) when treated with aq. KOH. (B) upon treatment with C_2 H_5 OH in presence of acid gave (C) which upon reducing with LiAIH_4 gave (D) and (E). (B) upon treatment with NH_3 followed by heating with P_4 O_(10) and subsequent hydrolysis gives back(B). Sodium salt of (B) on Kolbe's electrolysis gave 2, 3-dimethylbutane at anode. Structural formula of compound (C) is

An organic compound A(C_4 H_7 C_(13)) yields(B) when treated with aq. KOH. (B) upon treatment with C_2 H_5 OH in presence of acid gave (C) which upon reducing with LiAIH_4 gave (D) and (E). (B) upon treatment with NH_3 followed by heating with P_4 O_(10) and subsequent hydrolysis gives back(B). Sodium salt of (B) on Kolbe's electrolysis gave 2, 3-dimethylbutane at anode. Compound (D) and (E) respectively are

An organic compound A(C_4 H_7 C_(13)) yields (B) when treated with aq. KOH. (B) upon treatment with C_2 H_5 OH in presence of acid gave (C) which upon reducing with LiAIH_4 gave (D) and (E). (B) upon treatment with NH_3 followed by heating with P_4 O_(10) and subsequent hydrolysis gives back (B). Sodium salt of (B) on Kolbe's electrolysis gave 2, 3-dimethylbutane at anode. Structural formula of compound (C) is

An organic compound A(C_4 H_7 C_(13)) yields (B) when treated with aq. KOH. (B) upon treatment with C_2 H_5 OH in presence of acid gave (C) which upon reducing with LiAIH_4 gave (D) and (E). (B) upon treatment with NH_3 followed by heating with P_4 O_(10) and subsequent hydrolysis gives back (B). Sodium salt of (B) on Kolbe's electrolysis gave 2, 3-dimethylbutane at anode. Compound (D) and (E) respectively are

An organic compound A(C_4 H_7 C_(13)) yields (B) when treated with aq. KOH. (B) upon treatment with C_2 H_5 OH in presence of acid gave (C) which upon reducing with LiAIH_4 gave (D) and (E). (B) upon treatment with NH_3 followed by heating with P_4 O_(10) and subsequent hydrolysis gives back (B). Sodium salt of (B) on Kolbe's electrolysis gave 2, 3-dimethylbutane at anode. The dehydration of compound (D) gives