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The ratio of radii of first orbits of H,...

The ratio of radii of first orbits of H, `He^(+)` and `Li^(2+)` is:

A

`1:2:3`

B

`6:3:2`

C

`1:4:9`

D

`9:4:1`

Text Solution

AI Generated Solution

The correct Answer is:
To find the ratio of the radii of the first orbits of H, He\(^+\), and Li\(^{2+}\), we can use the formula for the radius of the nth orbit in a hydrogen-like atom: \[ r_n = \frac{n^2}{Z} \cdot r_0 \] where: - \(r_n\) is the radius of the nth orbit, - \(Z\) is the atomic number, - \(r_0\) is the radius of the first orbit of hydrogen, which is approximately \(0.529 \, \text{Å}\), - \(n\) is the principal quantum number (for the first orbit, \(n = 1\)). ### Step 1: Calculate the radius for Hydrogen (H) For hydrogen, \(Z = 1\): \[ r_H = \frac{1^2}{1} \cdot r_0 = 1 \cdot r_0 = r_0 \] ### Step 2: Calculate the radius for Helium ion (He\(^+\)) For helium ion, \(Z = 2\): \[ r_{He^+} = \frac{1^2}{2} \cdot r_0 = \frac{1}{2} r_0 \] ### Step 3: Calculate the radius for Lithium ion (Li\(^{2+}\)) For lithium ion, \(Z = 3\): \[ r_{Li^{2+}} = \frac{1^2}{3} \cdot r_0 = \frac{1}{3} r_0 \] ### Step 4: Form the ratio of the radii Now, we can express the ratio of the radii of H, He\(^+\), and Li\(^{2+}\): \[ \text{Ratio} = r_H : r_{He^+} : r_{Li^{2+}} = r_0 : \frac{1}{2} r_0 : \frac{1}{3} r_0 \] ### Step 5: Simplify the ratio To simplify the ratio, we can multiply each term by \(6\) (the least common multiple of the denominators 1, 2, and 3): \[ \text{Ratio} = 6 : 3 : 2 \] ### Final Answer Thus, the ratio of the radii of the first orbits of H, He\(^+\), and Li\(^{2+}\) is: \[ \boxed{6 : 3 : 2} \]

To find the ratio of the radii of the first orbits of H, He\(^+\), and Li\(^{2+}\), we can use the formula for the radius of the nth orbit in a hydrogen-like atom: \[ r_n = \frac{n^2}{Z} \cdot r_0 \] where: - \(r_n\) is the radius of the nth orbit, ...
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