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If K(sp) of Mg(OH)(2) is 1.2 xx 10^(-11)...

If `K_(sp)` of `Mg(OH)_(2)` is `1.2 xx 10^(-11)` . Then the highest pH of the 0.1 M solution of `Mg^(2+)` ion from which `Mg(OH)_(2)` is not precipitated is

A

4.96

B

6.96

C

7.54

D

9.04

Text Solution

Verified by Experts

The correct Answer is:
D

`K_(sp)` of `Mg(OH)_(2)` is given by
`K_(sp)=[Mg^(2+)][OH^(-)]^(2)`
or `[OH^(-)]=K_(sp)//[Mg^(2+)]`
`=(1.2 xx 10^(-11))/(1xx10^(-1))=1.2 xx 10^(-10)`
`:. [OH^(-)]=1.1 xx 10^(-5)M`
`pOH =-log (1.1 xx 10^(-5))` or `5 - log (1.1)`
`=4.958`
`pH =14-4.958=9.04`
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