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The most stable carbonium ion among the ...

The most stable carbonium ion among the following is

A

`C_(6)H_(5)overset(+)CHC_(6)H_(5)`

B

`C_(6)H_(5)overset(+)CH_(2)`

C

`CH_(3)overset(+)CH_(2)`

D

`C_(6)H_(5)CH_(2)overset(+)CH_(2)`

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The correct Answer is:
To determine the most stable carbonium ion (carbocation) from the given options, we will analyze the stability of each structure based on resonance and inductive effects. ### Step-by-Step Solution: 1. **Identify the Structures**: - The first structure has two phenyl groups attached to a carbon atom with a positive charge (C6H5-CH^+-C6H5). - The second structure has one phenyl group and a positive charge on a carbon atom adjacent to a CH2 group (C6H5-CH^+-CH2). - The third structure has a positive charge on a carbon atom adjacent to two hydrogen atoms (CH3-CH^+-CH2). - The fourth structure has a positive charge on a carbon atom adjacent to two CH2 groups (C6H5-CH2-CH^+-CH2). 2. **Analyze Resonance Effects**: - In the first structure, the positive charge can be delocalized over the two phenyl groups through resonance. This delocalization stabilizes the positive charge significantly. - In the second structure, the positive charge is only partially stabilized by the single phenyl group. There is some resonance, but it is less effective than in the first structure. - The third structure has no resonance stabilization as the positive charge is not adjacent to any electron-donating groups. It is only stabilized by the inductive effect from the CH3 group. - The fourth structure has no resonance stabilization either, as the positive charge is not in direct conjugation with any phenyl group. 3. **Evaluate Inductive Effects**: - The third structure (CH3-CH^+-CH2) has a +I effect from the CH3 group, which provides some stabilization. - The fourth structure (C6H5-CH2-CH^+-CH2) has no significant stabilization due to the lack of resonance. 4. **Rank the Stability**: - The first structure is the most stable due to extensive resonance stabilization. - The second structure is less stable than the first but more stable than the third and fourth due to some resonance. - The third structure is more stable than the fourth due to the +I effect from the CH3 group. - The fourth structure is the least stable due to the absence of resonance and inductive effects. 5. **Conclusion**: - The most stable carbonium ion among the given options is the first structure (C6H5-CH^+-C6H5) due to the resonance stabilization provided by the two phenyl groups. ### Final Answer: The most stable carbonium ion among the following is the first structure (C6H5-CH^+-C6H5). ---

To determine the most stable carbonium ion (carbocation) from the given options, we will analyze the stability of each structure based on resonance and inductive effects. ### Step-by-Step Solution: 1. **Identify the Structures**: - The first structure has two phenyl groups attached to a carbon atom with a positive charge (C6H5-CH^+-C6H5). - The second structure has one phenyl group and a positive charge on a carbon atom adjacent to a CH2 group (C6H5-CH^+-CH2). - The third structure has a positive charge on a carbon atom adjacent to two hydrogen atoms (CH3-CH^+-CH2). ...
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DINESH PUBLICATION-BASIC PRINCIPLES OF ORGANIC CHEMISTRY-REVISION QUESTIONS FROM COMPETITIVE EXAMS.
  1. Which of the following statements is false about resonance contributio...

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  2. The order of decreasing stability of the carbanions : (CH(3))(3)C^(-...

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  3. The most stable carbonium ion among the following is

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  4. The reaction CH(2)=CH-CH(3)+HBrrarrCH(3)underset(Br)underset(|)CHCH(...

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  5. Electrophile in the case of chlorination of benzene in presence of FeC...

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  6. Among the given molecule, what is the number of molecules which show r...

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  7. Which of the following is correct regarding the -I-effect of the subst...

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  8. Heterolytic fission of a covalent bond in organic molecules gives

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  9. How many of the following species is/are electrophile? H(2)O NH(3) AlC...

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  10. Point out incorrect statement about resonance

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  11. Which of the following is the active species in the nitration of aroma...

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  12. Which of the following is least stable carbonium ion ?

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  13. Which of the following behaves both as a nucleophile and as an electro...

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  14. Intermediate involved in Reimer-Tiemann reaction is

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  15. Among the following alkenes: {:(1-"Butene,",cis-2-"Butene",,"trans"-...

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  16. Most stable carbanion among the following is

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  17. The addition of HCN to carbonyl compounds is an example of

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  18. For the reaction of phenol with CHCl(3) in presence of KOH, the electr...

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  19. Nucleophilicity order is correctly represented by

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  20. In which of the following homolytic bond fission takes place ?

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