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For the reaction of phenol with CHCl(3) ...

For the reaction of phenol with `CHCl_(3)` in presence of KOH, the electrophile is

A

`overset(+)CHCl_(2)`

B

`:C"C"l_(2)`

C

`overset(cdot)CHCl_(2)`

D

`"C"Cl_(4)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the electrophile in the reaction of phenol with CHCl₃ in the presence of KOH, we can follow these steps: ### Step 1: Identify the Reactants The reactants in this reaction are phenol (C₆H₅OH) and chloroform (CHCl₃) in the presence of a strong base, KOH. **Hint:** Look for the components involved in the reaction to understand their roles. ### Step 2: Understand the Role of KOH KOH acts as a strong base that will deprotonate phenol, generating a phenoxide ion (C₆H₅O⁻). This ion is more nucleophilic than phenol itself. **Hint:** Consider how strong bases interact with acidic protons to form more reactive species. ### Step 3: Analyze the Reaction of CHCl₃ with KOH When CHCl₃ reacts with KOH, it undergoes a reaction that leads to the formation of dichlorocarbene (CCl₂). The KOH facilitates the removal of a hydrogen atom from CHCl₃, resulting in the generation of CCl₂. **Hint:** Focus on how halogenated compounds can react with bases to form reactive intermediates. ### Step 4: Identify the Electrophile In this reaction, the electrophile is the dichlorocarbene (CCl₂) that is generated. This species is highly reactive and can attack the nucleophilic phenoxide ion formed from phenol. **Hint:** Recall that an electrophile is a species that accepts an electron pair, typically a positively charged or electron-deficient species. ### Step 5: Conclusion Thus, the electrophile in the reaction of phenol with CHCl₃ in the presence of KOH is CCl₂. **Final Answer:** The electrophile is CCl₂. ---

To determine the electrophile in the reaction of phenol with CHCl₃ in the presence of KOH, we can follow these steps: ### Step 1: Identify the Reactants The reactants in this reaction are phenol (C₆H₅OH) and chloroform (CHCl₃) in the presence of a strong base, KOH. **Hint:** Look for the components involved in the reaction to understand their roles. ### Step 2: Understand the Role of KOH ...
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DINESH PUBLICATION-BASIC PRINCIPLES OF ORGANIC CHEMISTRY-REVISION QUESTIONS FROM COMPETITIVE EXAMS.
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  2. The addition of HCN to carbonyl compounds is an example of

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  3. For the reaction of phenol with CHCl(3) in presence of KOH, the electr...

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  4. Nucleophilicity order is correctly represented by

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  5. In which of the following homolytic bond fission takes place ?

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  6. Polarization of electrons in acrolein may be written as:

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  7. Select the most stable carbocation from amongst the following

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  8. Which of the following is not a nucleophile ?

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  9. Among the following, the true property about

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  10. Consider the following carbocations (I)C(6)H(5)overset(+)CH(2) , (II...

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  11. Intermediate formed during reaction of RCONH(2) with Br(2) and KOH are...

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  12. Acetaldehyde is the rearragement product of

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  13. In the mechanism of Hoffmann reaction which intermediate rearranges to...

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  14. Which of the following is most stable ?

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  15. The reaction (CH(3))(3)Cbroverset(H(2)O)rarr(CH(3))(3)C-OH is

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  16. The arrangement of (CH(3))(3)C-,(CH(3))(2)CH-, CH(3)CH(2)- when attach...

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  17. Choose the correct option which isomer for the given structure

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  18. Which of the following statements regarding the resonance energy of be...

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  19. The compound having only primary hydrogen atoms is

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