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Examine the following two structures for...


Examine the following two structures for the anilinium ion and choose the correct statement from the ones given below:

A

II is not an aceptable canonical structure because carbonium ions are less stable than ammonium ions

B

II is not the acceptable structure because it is non aromatic

C

II is not the acceptable canonical structure because the nitrogen has 10 valence electrons.

D

II is an acceptable canonical structure.

Text Solution

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The correct Answer is:
B, C

A carbanion ion is less stable than ammonium ion and nitrogen cannot expand its octet to accommodate 10 valence electrons.
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DINESH PUBLICATION-BASIC PRINCIPLES OF ORGANIC CHEMISTRY-SELECTED STRAIGHT OBJECTIVE TYPE MCQS
  1. Which of the following species are planar ?

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  2. The greater stability of tert-butyl carbocation than methyl carbocatio...

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  3. Examine the following two structures for the anilinium ion and choose ...

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  4. An aromatic molecule will

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  5. Resonance structure of a molecule cannot have

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  6. Which one of the following acids would you expect to be the strongest ...

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  7. Amongst the following the most basic compound is :

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  8. Homolytic fission of carbon-carbon bond of ethane produces an intermed...

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  9. The decreasing order of strength of the bases, OH^(-), NH(2)^(-), H-C-...

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  10. Which of the following has the smallest heat of hydrogenation per mole...

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  11. The kind of delocalisation involving sigma bond orbitals is called………....

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  12. The intermediate during the addition of HCl to propene in the presence...

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  13. In the following compounds The order of basicity is

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  14. The formation of cyanohydrin from ketone is an example of :

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  15. Polarisation of electrons in acrolein may be written as :

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  16. The most unlikely representation of resonance structure of p-nitrophen...

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  17. Which of the following alkenes will react fastest with H(2) under cata...

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  18. Which of the following has highest nucleophilicity ?

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  19. The reaction of propene with HOCl proceeds via the addition of :

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  20. Which is most stable ?

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