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The increasing order of stability of the...

The increasing order of stability of the following free radicals is:

A

`(CH_(3))_(2)overset(cdot)CHlt(CH_(3))_(3)overset(cdot)Clt(C_(6)H_(5))_(2)overset(cdot)CHlt(C_(6)H_(5))_(3)overset(cdot)C`

B

`(C_(6)H_(5))_(3)overset(cdot)Clt(C_(6)H_(5))_(2)overset(cdot)CHlt(CH_(3))_(3)overset(cdot)Clt(CH_(3))_(2)overset(cdot)CH`

C

`(C_(6)H_(5))_(2)overset(cdot)CHlt(C_(6)H_(5))_(3)overset(cdot)Clt(CH_(3))_(3)overset(cdot)Clt(CH_(3))_(2)overset(cdot)CH`

D

`(CH_(3))_(2)overset(cdot)CHlt(CH_(3))_(3)overset(cdot)Clt(C_(6)H_(5))_(3)overset(cdot)Clt(C_(6)H_(5))_(2)overset(cdot)CH`

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The correct Answer is:
A

More the number of phenyl groups, greater is the stabilization due to resonance, therefore, `(C_(6)H_(5))_(3)overset(cdot)C` is more stable than `(C_(6)H_(5))overset(cdot)CH.` Further, more the number of methyl groups, more is the number of hyperconjugation structures and hence more stable is the radical, i.e., `(CH_(3))_(3)overset(cdot)C`. is more stable than `(CH_(3))_(2)overset(cdot)CH.` Hence option (A) is correct
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DINESH PUBLICATION-BASIC PRINCIPLES OF ORGANIC CHEMISTRY-SELECTED STRAIGHT OBJECTIVE TYPE MCQS
  1. Consider the following reaction: CH(3)underset(D)underset(|)CH-under...

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  2. Which among the following is the most stable carbocation ?

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  3. The names of some compounds are given. Which one not in the IUPAC syst...

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  4. Due to the presence of an unpaired electron free radicals are

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  5. The IUPAC name of C(6)H(5)COCl is

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  6. IUPAC name of

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  7. The general molecular formula, which represents the homologous series ...

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  8. The increasing order of stability of the following free radicals is:

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  9. The IUPAC name of the compound shown below is

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  10. IUPAC name of

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  11. Among the following, the least stable resonance structure is :

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  12. In the hydrocarbon underset(6)underset()(CH(3))-underset(5)underset()(...

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  13. The correct decreasing order of priority for the functional groups of ...

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  14. Hyperconjugation involves overlap of the following orbitals :

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  15. The correct of stability for the following species is :

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  16. The stability of carbanions in the following (i) RC-=overset(-)overs...

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  17. The IUPAC name of the following compound is

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  18. Arrange the carbanions, (CH(3))(3)bar(C),bar(C)Cl(3),(CH(3))(2)bar(C)H...

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  19. The IUPAC name of the compound having the formula CH-=C-CH=CH(2) is

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  20. The IUPAC name of neopentane is

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