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Arrange the following carbonium ions in ...

Arrange the following carbonium ions in order of decreasing stability :
`underset(I)underset()((CH_(3))_(3)overset(+)C)" "underset(II)underset()((CH_(3))_(2)overset(+)CH)" "underset(III)underset()(CH_(3)overset(+)CH_(2))" "underset(IV)underset()(overset(+)H_(3)C)`

A

`IIgtIIIgtIgtIV`

B

`IVgtIIIgtIIgtI`

C

`IgtIIgtIIIgtIV`

D

`IgtIIgtIIIgtIV`

Text Solution

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The correct Answer is:
C

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Arrange the following free radicals in order of stability underset(I)underset()((CH_(3))_(3)overset(cdot)C)" "underset(II)underset()((CH_(3))_(2)overset(cdot)CH)" "underset(III)underset()(CH_(3)overset(cdot)CH_(2))" "underset(IV)underset()(overset(cdot)CH_(3))

Arrange the following carbocations in order of increasing stability : {:(underset("(I)")((CH_(3))_(3)Coverset(+)CH_(2))", "underset("(II)")((CH_(3))_(3)overset(+)C)","),(underset("(III)")(CH_(3)CH_(2)overset(+)CH_(2))", "underset("(IV)")(CH_(3)overset(+)CHCH_(2)CH_(3))):}

The decreasing order of the stability of the ions underset((I))underset()(CH_(3)-overset(+)CH-CH_(3)), underset((II))underset()(CH_(3)-overset(+)CH-OCH_(3)), , underset((III))underset()(CH_(3)-overset(+)CH-COCH_(3)),

The stability of carbocations underset(I)underset()((CH_(3))_(3)C^(oplus))" "underset(II)underset()((CH_(3))_(2)overset(oplus)C(OCH_(3)))" "underset(III)underset()(CH_(3)CH_(2)CH_(2)overset(oplus)CH_(2))" "underset(IV)underset()(CH_(3)overset(oplus)CHCH_(2)CH_(3)) follows the order

CH_(3)underset(Br)underset(|)CH-overset(CH_(3))overset(|)underset(OH)underset(|)(C)-C-O-CH_(3)

Arrange the following according to increasing stability: underset((I))(CH_(3)CH_(2)CH_(2)overset(+)(CH_(2))) , underset((II))((CH_(3))_(3)overset(+)(C)) , underset((III))(CH_(3),CH_(3)CH_(2)overset(+)(CH_(3)))

CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-CH_(2)-underset(O)underset(||)(C)-NHCH_(3)

CH_(3)-underset(CH_(3))underset(|)(C)=CH-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-CH_(3)

The decreasing order of the stability of the ions : underset((I))(CH_(3)=overset(+)(C)H-CH_(3))" "underset((II))(CH_(3)-overset(+)(C)H-OCH_(3))" "underset((III))(CH_(3)-overset(+)(C)H-COCH_(3)^(-))

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