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Which of the following order is correct ...

Which of the following order is correct for the decreasing reactivity to ring monobromination of the following compounds?

A

` I gt II gt III gt IV`

B

`I gt III gt II gt IV`

C

`II gt III gt IV gt I`

D

`III gt I gt III gt IV`

Text Solution

Verified by Experts

The correct Answer is:
B

Bromination of arenes is an electrophilic substitution reaction. The higher the electron density on the benzene ring, more is the ease with which the ring undergoes substitution. The presence of +R effect increases the reactivity while -R effect decreases it
`NO_(2)` is more deactivating than `-COOH` since N is +vely charged and withdraws more electrons form benzene than `-COOH`
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