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An alkene has moleuclar mass in the rang...

An alkene has moleuclar mass in the range of 80-85. A 10.02mg of its sample took up 8.4mL of `H_(2)` gas measured at `0^(@)C` and 760 mn pressure. Upon ozonolysis it yielded glyoxal and methanol. The alkene is

A

Hexane-1

B

Hexyne-1

C

1,3-Hexadien

D

1,3,5-Hexatriene

Text Solution

Verified by Experts

The correct Answer is:
D

Vol. of `H_(2)` at NTP=8.4mL
Moles of `H_(2)=(8.4mL)/ (22400mL"mol") =3.7xx10^(-4)`
Mol of alkene = 10.02mg=`10.02xx10^(-3)g`
mol. Mass of alkene =80g`mol^(-1)`
Mol pf alkene=`(10.2xx10^(-3)g)/(80mgmol^(-))` =`1.25xx10^(4)mol`
`thererfore` 1 mol of alkene `-=3 "mol of" H_(2)`
Therefore, products of ozonolysis should be 2 moles each of glyoxal and methanl.
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