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An alkyl halide (X)of the folmula C(6)H(...

An alkyl halide `(X)`of the folmula `C_(6)H_(13)Cl` on treatment with potassium tertiary butoxide gives two isomeric alkenes `(Y)` and `(Z)(C_(6)H_(12))`. Both the alkenes on hydrogenation give `2,3-`dimethyl butane. Perdict the structures of `(X),(Y)` , and `(Z)`

A

`CH_(2)=overset(CH_(3))overset("| ")("C ")-overset(CH_(3))overset("| ")("C ")H-CH_(3)` and `CH_(2)=overset(CH_(3))overset("| ")("C ")-overset(CH_(3))overset("| ")("C ")H-CH_(3)`

B

`CH_(2)=overset(CH_(3))overset("| ")("C ")-overset(CH_(3))overset("| ")("C ")H-CH_(3)` and `CH_(3)-CH=CH-C_(3)H_(7)`

C

`CH_(2)-CH=CH-C_(3)H_(7)` and `(CH_(3))_(2)C=C(CH_(3))_(2)`

D

`CH_(2)=overset(CH_(3))overset("| ")("C ")-overset(CH_(3))overset("| ")("C ")H-CH_(3)` and `CH_(3)-overset(CH_(3))overset("| ")("C ")=CHCH_(2)CH_(3)`

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Verified by Experts

The correct Answer is:
A

During `beta`-elimination of any alkyl halide we get two position isomeric alkenes (one in major yield, other in minor yield by Saytzeff's Rule), which differ only in the position of their double bonds. However their skeleton of carbon chains isomers. Accordingly choices B, C, D represent chain isomers hence are incorrect, while option A representing position isomers is correct.
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DINESH PUBLICATION-ORGANIC COMPOUNDS WITH FUNCTIONAL GROUP CONTAINING HALOGENS -UNIT TEST - 5
  1. An alkyl halide (X)of the folmula C(6)H(13)Cl on treatment with potass...

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  2. Which one is not true for all the members of a homologous series

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  3. The number of secondary atoms in the following compounds are CH(3)un...

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  4. The alkane which has only primary hydrogen atoms is

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  5. Which of the following compounds have isopropyl group

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  6. The IUPAC name of following compound is {:(CH(2)=C-CH(2)-CH(3)),(" ...

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  7. The IUPAC name of is

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  8. The IUPAC name of the compound is

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  9. The IUPAC name of the followin poly functional

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  10. Assingn the IUPAC name to the following compound

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  11. The IUPAC name of

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  12. Mistake in the name but-1-ene ol is

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  13. Racemic mixture is formed ny mixing two:

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  14. Geometrical isomerism is not shon by

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  15. Among the following four structures I to IV I {:(" "CH(3))...

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  16. Which of the following compounds will show meso isomer ?

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  17. Which of the following compounds will show metamerism ?

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  18. Correct order of nucleophilicity is

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  19. The basic strength of underset(I)(CH-=C), underset(II)(CH(2)=CH), un...

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  20. Consider the following carbanions Correct order of stability is

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  21. Different hydrogen in overset(a)(C )H(3)overset(b)(C )H=overset(b)(C...

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