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In the following sequence of the reactio...

In the following sequence of the reactions :
`CH_(3)CH_(2)CH_(2)I overset(KOH(Alc.))rarr A overset((i) Br_(2))underset((ii) alc. KOH)rarr B overset(Na//NH_(3))rarr C`
The end product C is :

A

Alkene

B

Alkanol

C

Alkyne

D

Alkyl amine

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The correct Answer is:
To determine the end product C from the given sequence of reactions starting with iodopropane (CH₃CH₂CH₂I), we will go through each step methodically. ### Step 1: Reaction with Alcoholic KOH - **Starting Compound:** CH₃CH₂CH₂I (1-iodopropane) - **Reagent:** KOH (alcoholic) - **Type of Reaction:** Dehydrohalogenation - **Process:** The alcoholic KOH will facilitate the elimination of HI (hydrogen iodide) from the iodopropane. This is a beta-elimination reaction where the iodine (I) is removed from the alpha carbon and a hydrogen (H) is removed from the beta carbon. - **Product A:** The product after this step will be propene (CH₃CH=CH₂). ### Step 2: Reaction with Br₂ - **Starting Compound:** Product A (CH₃CH=CH₂) - **Reagent:** Br₂ - **Type of Reaction:** Electrophilic addition - **Process:** The double bond in propene will react with bromine (Br₂), resulting in the addition of bromine across the double bond. - **Product B:** The product after this step will be 1,2-dibromopropane (CH₃CHBrCH₂Br). ### Step 3: Reaction with Alcoholic KOH - **Starting Compound:** Product B (CH₃CHBrCH₂Br) - **Reagent:** KOH (alcoholic) - **Type of Reaction:** Dehydrohalogenation - **Process:** Again, alcoholic KOH will facilitate the elimination of HBr. In this case, two HBr molecules will be eliminated (one from each of the brominated carbons), resulting in the formation of a triple bond. - **Product C:** The product after this step will be 1-butyne (CH₃C≡CCH₃). ### Step 4: Reaction with Sodium in NH₃ - **Starting Compound:** Product C (CH₃C≡CCH₃) - **Reagent:** Sodium (Na) in liquid ammonia (NH₃) - **Type of Reaction:** Reduction - **Process:** Sodium in liquid ammonia will reduce the alkyne to a cis or trans alkene. The predominant product will be trans-alkene due to the mechanism of the reduction. - **Final Product:** The final product will be trans-2-butene (CH₃CH=CHCH₃). ### Summary of the Reaction Sequence: 1. CH₃CH₂CH₂I + KOH (alc.) → CH₃CH=CH₂ (Propene) 2. CH₃CH=CH₂ + Br₂ → CH₃CHBrCH₂Br (1,2-Dibromopropane) 3. CH₃CHBrCH₂Br + KOH (alc.) → CH₃C≡CCH₃ (1-Butyne) 4. CH₃C≡CCH₃ + Na/NH₃ → trans-2-Butene ### Final Answer: The end product C is trans-2-butene (CH₃CH=CHCH₃). ---

To determine the end product C from the given sequence of reactions starting with iodopropane (CH₃CH₂CH₂I), we will go through each step methodically. ### Step 1: Reaction with Alcoholic KOH - **Starting Compound:** CH₃CH₂CH₂I (1-iodopropane) - **Reagent:** KOH (alcoholic) - **Type of Reaction:** Dehydrohalogenation - **Process:** The alcoholic KOH will facilitate the elimination of HI (hydrogen iodide) from the iodopropane. This is a beta-elimination reaction where the iodine (I) is removed from the alpha carbon and a hydrogen (H) is removed from the beta carbon. - **Product A:** The product after this step will be propene (CH₃CH=CH₂). ...
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DINESH PUBLICATION-ORGANIC COMPOUNDS WITH FUNCTIONAL GROUP CONTAINING HALOGENS -UNIT TEST - 5
  1. In the following sequence of the reactions : CH(3)CH(2)CH(2)I overse...

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  2. Which one is not true for all the members of a homologous series

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  3. The number of secondary atoms in the following compounds are CH(3)un...

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  4. The alkane which has only primary hydrogen atoms is

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  5. Which of the following compounds have isopropyl group

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  6. The IUPAC name of following compound is {:(CH(2)=C-CH(2)-CH(3)),(" ...

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  7. The IUPAC name of is

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  8. The IUPAC name of the compound is

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  9. The IUPAC name of the followin poly functional

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  10. Assingn the IUPAC name to the following compound

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  11. The IUPAC name of

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  12. Mistake in the name but-1-ene ol is

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  13. Racemic mixture is formed ny mixing two:

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  14. Geometrical isomerism is not shon by

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  15. Among the following four structures I to IV I {:(" "CH(3))...

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  16. Which of the following compounds will show meso isomer ?

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  17. Which of the following compounds will show metamerism ?

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  18. Correct order of nucleophilicity is

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  19. The basic strength of underset(I)(CH-=C), underset(II)(CH(2)=CH), un...

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  20. Consider the following carbanions Correct order of stability is

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  21. Different hydrogen in overset(a)(C )H(3)overset(b)(C )H=overset(b)(C...

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