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CH(3)CH(2)CH(2)Cl overset(alc. KOH)rarr ...

`CH_(3)CH_(2)CH_(2)Cl overset(alc. KOH)rarr B overset(HBr)rarr C overset("Na//ether")rarr D`
In the above reaction, the product D is

A

Propane

B

2,3-Dimethylbutane

C

Hexane

D

Allyl bromine

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The correct Answer is:
To solve the given reaction sequence, we will go through each step one by one. ### Step 1: Starting Material The starting material is **CH₃CH₂CH₂Cl** (1-chloropropane). ### Step 2: Reaction with Alcoholic KOH When 1-chloropropane reacts with alcoholic KOH, a dehydrohalogenation reaction occurs. This means that a hydrogen atom and the chlorine atom are eliminated, leading to the formation of an alkene. - **Mechanism**: The KOH acts as a base and abstracts a beta-hydrogen from the beta-carbon (the carbon adjacent to the one bonded to chlorine). The chlorine leaves as a chloride ion, resulting in the formation of a double bond. - **Product**: The product formed is **CH₃CH=CH₂** (propene). ### Step 3: Reaction with HBr Next, the alkene (propene) reacts with HBr. This is an addition reaction where HBr adds across the double bond. - **Markovnikov's Rule**: According to Markovnikov's rule, the hydrogen atom from HBr will attach to the carbon with more hydrogen atoms (the less substituted carbon), while the bromine will attach to the carbon with fewer hydrogen atoms. - **Product**: The product of this reaction will be **CH₃CHBrCH₃** (2-bromopropane). ### Step 4: Reaction with Sodium in Dry Ether Finally, 2-bromopropane reacts with sodium in dry ether. This is a Wurtz reaction, which leads to the formation of an alkane. - **Mechanism**: In the presence of sodium, the bromine atom is removed, and a new carbon-carbon bond is formed between the two alkyl groups. - **Product**: The product formed is **C₆H₁₄** (hexane), specifically **n-hexane**. ### Final Product Thus, the final product D is **n-hexane**. ---

To solve the given reaction sequence, we will go through each step one by one. ### Step 1: Starting Material The starting material is **CH₃CH₂CH₂Cl** (1-chloropropane). ### Step 2: Reaction with Alcoholic KOH When 1-chloropropane reacts with alcoholic KOH, a dehydrohalogenation reaction occurs. This means that a hydrogen atom and the chlorine atom are eliminated, leading to the formation of an alkene. ...
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DINESH PUBLICATION-ORGANIC COMPOUNDS WITH FUNCTIONAL GROUP CONTAINING HALOGENS -UNIT TEST - 5
  1. CH(3)CH(2)CH(2)Cl overset(alc. KOH)rarr B overset(HBr)rarr C overset("...

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  2. Which one is not true for all the members of a homologous series

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  3. The number of secondary atoms in the following compounds are CH(3)un...

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  4. The alkane which has only primary hydrogen atoms is

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  5. Which of the following compounds have isopropyl group

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  6. The IUPAC name of following compound is {:(CH(2)=C-CH(2)-CH(3)),(" ...

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  7. The IUPAC name of is

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  8. The IUPAC name of the compound is

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  9. The IUPAC name of the followin poly functional

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  10. Assingn the IUPAC name to the following compound

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  11. The IUPAC name of

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  12. Mistake in the name but-1-ene ol is

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  13. Racemic mixture is formed ny mixing two:

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  14. Geometrical isomerism is not shon by

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  15. Among the following four structures I to IV I {:(" "CH(3))...

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  16. Which of the following compounds will show meso isomer ?

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  17. Which of the following compounds will show metamerism ?

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  18. Correct order of nucleophilicity is

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  19. The basic strength of underset(I)(CH-=C), underset(II)(CH(2)=CH), un...

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  20. Consider the following carbanions Correct order of stability is

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  21. Different hydrogen in overset(a)(C )H(3)overset(b)(C )H=overset(b)(C...

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