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C-Cl bond of chlorobenzene in comparison...

C-Cl bond of chlorobenzene in comparison to C-Cl bond of methyl chloride is

A

longer and weaker

B

shorter and weaker

C

shorter and stronger

D

longer and stronger

Text Solution

Verified by Experts

The correct Answer is:
C
Shorter and stronger, due to resonance.
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Explore conceptually related problems

The C-Cl bond in chlorobenzene as compared with C-Cl bond in methyl chloride is ___________.

Give reasons: (i). C-Cl bond length in chlorobenzene is shorter than C-Cl bond length in CH_(3)-Cl (ii). The dipole moment of chlorobenzene is less than of cyclohexyl chloride. (c). S_(N^(1)) reactions are are accompanied by racemisation is optically active alkyl halides.

Assertion: It is difficult to replace chlorine by -OH in chlorobenzene in comparison to that in chloroethane Reason: Chlorine-carbon (C-Cl) bond in chlorobenzene has a partial double bond character due to resonance.

DINESH PUBLICATION-ORGANIC COMPOUNDS WITH FUNCTIONAL GROUP CONTAINING HALOGENS -Revision Questions From Competitive Exams
  1. The reaction of t-Butylbromide with sodium methoxide produces mainly

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  2. The reaction of 4-bromobenzyl chloride with NaCN in ethanol leads to :

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  3. C-Cl bond of chlorobenzene in comparison to C-Cl bond of methyl chlori...

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  4. C-X bond is strongest in :

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  5. Insecticide Gammexane is

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  6. The final product formed by distilling ethyl alcohol with excess of Cl...

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  7. For converting aniline into chlorobenzene which of the following regen...

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  8. Silver benzonate will react with bromine in acetone to give

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  9. The alkyl halide is converted into an alcohol by

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  10. C(3)H(8)+CI(2)overset(Light)toC(3)H(7)CI+HCI is an example of which of...

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  11. The reaction CH(2)=CH-CH(3)+HBr rarr CH(3)-overset(Br)overset(|)(C )HC...

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  12. Which of the following compounds on oxidation gives benzoic acid ?

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  13. The chloroform reacts with NaOH to give

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  14. When ethyl iodide and n-propyl iodide are allowed to react with sodium...

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  15. Iodoethane reacts with sodium in ether, the product formed is

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  16. Which of the following reacts with chloroform and base to form phenyl ...

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  17. The reaction described below is :

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  18. The replacement of chlorine of chlorobenzene to give phenol requires d...

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  19. 1,3-Dibromopropane reacts with metallic zinc to form

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  20. C(6)H(6)Cl(6) can be obtained from :

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