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The decreasing order of reactivity of m-...

The decreasing order of reactivity of `m-`nitrobromobenzene (I0, 2, 4, 6-trinitrobromo-benzene (II), `p-`nitrobromobenzene (III), and 2,4-dinitrobromobenzene (IV), towards `OH^(-)` ions is:

A

`I gt II gt III gt IV`

B

`II gt IV gt III gt I`

C

`IV gt II gt III gt I`

D

`II gt IV gt I gt III`

Text Solution

Verified by Experts

The correct Answer is:
B

Reactivity decreases with the decrease in the number of `NO_(2)` group. M-nitromobenzene is however, still less reactive than o, or p-nitro isomers. This is because the `NO_(2)` at meta position cannot stabilise the intermediate carbocation.
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