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The halogen compound which most readily ...

The halogen compound which most readily undergoes nucleophilic substitution is

A

`CH_(2)=CHCl`

B

`CH_(3)CH=CHCl`

C

`CH_(2)=C(Cl)=CH_(2)`

D

`CH_(2)=CHCH_(2)Cl`

Text Solution

Verified by Experts

The correct Answer is:
D
In `CH_(2)=CHCH_(2)Cl` is attached to `sp^(3)` carbon while in all other compounds, Cl is attached to `sp^(2)` carbon. In other words, allyl chlorides are more reactive than vinyl and aryl chlorides.
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DINESH PUBLICATION-ORGANIC COMPOUNDS WITH FUNCTIONAL GROUP CONTAINING HALOGENS -Revision Questions From Competitive Exams
  1. Markownikoff rule is best applicable to

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  2. The compound Q is

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  3. The halogen compound which most readily undergoes nucleophilic substit...

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  4. Consider the following halogen containing compounds (i) CHCl(3) (ii...

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  5. Which is least reactive towards nucleophilic substitution (S(N^(2)))

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  6. An alkyl halide by formation of its Grignard ragent and heating with w...

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  7. Which one of the following is not the correct order of boiling points ...

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  8. The S(N^(1)) reactivity of the following halides will be in the order:...

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  9. A cyclic steroisomers having the molecular formula C(4)H(7)Cl are clas...

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  10. The major product P in the following reaction is CH(3)CH=CH(2)overset(...

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  11. Alkyl halides are less soluble in water because

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  12. Which of the following shows S(N^(1)) reaction most readily ?

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  13. C(2)H(5)OH+SOCl(2) overset("Pyridine")rarr x + y + z, in the reaction ...

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  14. Chloropropane and isopropyl chloride with sodium in ether forms

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  15. Tertiary butyl chloride preferably undergo hydrolysis by:

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  16. The alkyl halide that undergoes S(N)1 reaction more readily is

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  17. C(3)H(8)Ooverset(O)underset(K(2)Cr(2)"O"//H)rarrC(3)H(6)Ooverset(I(2))...

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  18. Given the following sequence of reactions CH(3)CH(2)I overset(KCN)ra...

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  19. What are X and Y in the following reaction sequence C(2)H(5)OH overs...

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  20. Consider the reaction C(2)H(5)Cl+AgCN overset(ErOH)rarr X

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