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Chloropropane and isopropyl chloride wit...

Chloropropane and isopropyl chloride with sodium in ether forms

A

2-methyl pentane

B

Hexane

C

3-methyl pentane

D

4-methyl pentane

Text Solution

Verified by Experts

The correct Answer is:
A
Tertiary halides preferably undergo `S_(N^(1))` substitution as they given suitable carbocation
`underset("t-butyl chloride")(CH_(3)-overset(CH_(3))overset("| ")underset(CH_(3))underset("| ")("C ")-Cloverset("slow")underset(-Cl)rarr)underset(("most stable"))underset(3^(@)"carbocation")((CH_(3))Coverset(_OH^(-))rarr)underset("t-butyl alcohol")((CH_(3))_(3)C-OH)`
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DINESH PUBLICATION-ORGANIC COMPOUNDS WITH FUNCTIONAL GROUP CONTAINING HALOGENS -Revision Questions From Competitive Exams
  1. Which of the following shows S(N^(1)) reaction most readily ?

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  2. C(2)H(5)OH+SOCl(2) overset("Pyridine")rarr x + y + z, in the reaction ...

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  3. Chloropropane and isopropyl chloride with sodium in ether forms

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  4. Tertiary butyl chloride preferably undergo hydrolysis by:

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  5. The alkyl halide that undergoes S(N)1 reaction more readily is

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  6. C(3)H(8)Ooverset(O)underset(K(2)Cr(2)"O"//H)rarrC(3)H(6)Ooverset(I(2))...

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  7. Given the following sequence of reactions CH(3)CH(2)I overset(KCN)ra...

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  8. What are X and Y in the following reaction sequence C(2)H(5)OH overs...

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  9. Consider the reaction C(2)H(5)Cl+AgCN overset(ErOH)rarr X

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  10. Hydrolysis of trichloromethane with aqueous KOH gives

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  11. Which compound does not give precipitate with ammonical silver nitrate...

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  12. The formula of choral is

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  13. Reaction of methyl bromide with aqueous sodium hydroxide involves …â...

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  14. Formation of transition state is a characteristic of

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  15. Reaction between propene and HCl to form isopropyl chloride takes plac...

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  16. CH(3)CH(2)CH(2)Br overset(alc. KOH)rarr CH(3)CH=CH(2)+HBr is an exmple...

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  17. Iodofrom can be prepared from all except

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  18. In the following sequence of reactions: CH(3)-Br overset(KCN)rarr A ...

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  19. Compound (A) C(8)H(9)Br. Gives a white precipitate when warmed with al...

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  20. KI in acetone undergoes S(N^(2)) reaction with each of P, Q, R, S. The...

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