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(CH(3))(3)-C-MgCl on reaction with D(2)O...

`(CH_(3))_(3)-C-MgCl` on reaction with `D_(2)O` produces

A

`(CH_(3))_(3)CD`

B

`(CH_(3))_(3)COD`

C

`(CD_(3))_(3)CD`

D

`(CD_(3))_(3)OD`

Text Solution

Verified by Experts

The correct Answer is:
A
`(CH_(3))_(3)C-Mg-Br+DOD rarr (CH_(3))_(3)CD+Mg(OD)Br`
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(CH_(3))_(3)CMgBr on reaction with D_(2)O produces :

Me_3 C-MgCl on reaction with D_2 O produces :

(CH_3)_3CMgCl on reaction with D_2O produces

Identify the total number of following compounds which liberate CH_(4) gas on reaction with CH_(3)MgCl (i) H_(2)O (ii) CH_(2)=CH_(2) (iii) Me-C-=C-H

Which S_(N)1 reaction would you expect to take place more rapidly ? (a) (i) (CH_(3))_(3)C Cl+H_(2)O to (CH_(3))_(3)COH+HCl Or (ii) (CH_(3))_(3)C Br+H_(2)O to (CH_(3))_(3)COH+HBr (b) (i) (CH_(3))_(3)C Cl+H_(2)O to (CH_(3))_(3)COH + HCl Or (ii) C_(5)H_(5)Cl+H_(2)O to C_(5)H_(5)OH + HCl (c) (i) (CH_(3))_(3)C Cl+ H_(2)O to (CH_(3))_(3)COH + HCl Or (ii) (CH_(3))_(3)C Cl+ CH_(3)OH to (CH_(3))_(3)COCH_(3)+ HCl (d) (i) (CH_(3))_(3)C Cl(1.0M)+CH_(3)CH_(2)O^(-)(1.0M) overset(C_(2)H_(2)OH)to (CH_(3))_(3)COCH_(2)CH_(3)+Cl^(-) Or (ii) (CH_(3))_(3)C Cl(1.0M)+CH_(3)CH_(2)O^(-)(2.0M) overset(C_(2)H_(2)OH)to (CH_(3))_(3)COCH_(2)CH_(3)+Cl^(-)

DINESH PUBLICATION-ORGANIC COMPOUNDS WITH FUNCTIONAL GROUP CONTAINING HALOGENS -Selected Straight Objective Type MCQs
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