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The correct order of increasing reactivi...

The correct order of increasing reactivity of C-X bond towards nucleophile in the following compounds is :

A

II lt III lt I lt IV

B

IV lt III lt I lt II

C

III lt II lt I lt IV

D

I lt II lt IV lt III

Text Solution

Verified by Experts

The correct Answer is:
D

(i) Among the given halides (i) aryl halides `(C_(6)H_(5)X)` is least reactive towards nucleophilic substitution because due to reaconance.
(ii) Electron withdrawing (groups =`NO_(2)` groups) at ortho and para position promotes easy displacement of -X of aryl halide.
(iii) Among alkyl halides `3^(@)` halides are more reactive in comparison to `2^(@)` halides because of the formation of more stable carbocation
`therefore` order of reactivity is.
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