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In the reaction underset("1-Chlorobut-...

In the reaction
`underset("1-Chlorobut-2-ene")(CH_(3)CH=CH-CH_(2)Cl)overset(CN^(-))rarr`
the organic product/product formed are

A

`CH_(3)CH=CH-CH_(2)CN`

B

`CH_(3)CH(CN)CH=CH_(2)`

C

Both A and B

D

None of these

Text Solution

Verified by Experts

The correct Answer is:
C

Formation of product (A) is due to `S_(N^(2))` reaction at the terminal C.

Formation of product (B) is due to the attack of `CN^(-)` on C-3 with the `pi`-electrons of double bond acting as nucleophile to displace `Cl^(-)` is an alylic rearrangement (an `S_(N^(2))` reaction).
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