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In their nucleophilic substitution react...

In their nucleophilic substitution reactions, aryl halide resembles

A

vinyl chloride

B

Allyl chloride

C

benzyl chloride

D

Ethyl chloride

Text Solution

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The correct Answer is:
A

Aryl halides undergo nucleophilic substitution with difficulty due to `sp^(2) C` of C-Cl bond in aryl halides i.e., more electronegativity of `sp^(2)C` and thus resembles with vinyl chloride.
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(a) Aryl halides are less reactive in nucleophilic substitution reactions. (i) Write any two reasons for less reactivity. (ii) Give one example for nucleophilic substitution reactions of aryl halides (b) Write a method for the preparation of alkyl halides. (c) Which of the following is not a polyhalogen compound. (i) Chloroform (ii) Freon (iii) Carbon tetrachloride (iv) Chlorobenzene

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DINESH PUBLICATION-ORGANIC COMPOUNDS WITH FUNCTIONAL GROUP CONTAINING HALOGENS -ULTIMATE PREPARATORY PACKAGE
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  9. In their nucleophilic substitution reactions, aryl halide resembles

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  14. A chloro derivative (A) on treatment with zinc - copper couple gives a...

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  17. The hydrolysis of 2-bromo-3-methylbutane by S(N^(1)) mechanism gives m...

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