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C(2)H(6)overset((CH(3)COO)(2)Mn)rarr X o...

`C_(2)H_(6)overset((CH_(3)COO)_(2)Mn)rarr X overset(PCl_(5))rarr Y overset(C_(6)H_(6))underset("Anhy." AlCl_(3))rarr Z`. Identify X, Y and Z :

A

`CO_(2), COCl, C_(6)H_(5)COCl`

B

`CO_(2), COCl, C_(6)H_(5)CH_(2)COCl`

C

`CH_(3)COOH, CH_(3)COCl, C_(6)H_(5)COCH_(3)`

D

`HCOOH, HCOCl, C_(6)H_(5)CHO`

Text Solution

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The correct Answer is:
C

`C_(2)H_(6)overset((CH_(3)COO)_(2)Mn)rarr underset((X))(CH_(3))COOH overset(PCl_(5))rarr`
`underset((Y))(H_(3)C-overset(O)overset(||)(C )-Cl)overset(Anhy. AlCl_(3))underset(C_(6)H_(6))rarr underset("Acetophenone(Z)")(C_(6)H_(5)-overset(O)overset(||)(C )-CH_(3))`
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DINESH PUBLICATION-ORGANIC COMPOUNDS WITH FUNCTIONAL GROUP CONTAINING HALOGENS -BRAIN TEASERS - 9
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