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An organic compound A (C(4)H(10)O) has t...

An organic compound A `(C_(4)H_(10)O)` has two enantiomeric forms and on dehydration it gives B (major product) and C (minor product). B and C are treated with HBr/Peroxide and the compounds so produced were subjected to alkaline hydrolysis then

A

B will given an isomer of A

B

C will give an isomer of A

C

Neither of then will give isomer of A

D

Both B and C will give isomer of A

Text Solution

Verified by Experts

The correct Answer is:
B
(A) is `CH_(3)CH_(2)-overset(OH)overset("| ")("C ")H-CH_(3) overset(H_(2)SO_(4))rarr underset(("Major")B)(CH_(3)CH=CH-CH_(3))+CH_(2)= underset(("Minor")C)(CHCH_(2)CH_(3))`
Addition in C will occur against Markownikov's rule. Hence C will give isomer of (A) i.e., it will form 1-Butanol.
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DINESH PUBLICATION-ORGANIC COMPOUNDS WITH FUNCTIONAL GROUP CONTAINING HALOGENS -BRAIN TEASERS - 10
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  8. Consider the reaction Choose the correct statement

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  9. An organic compound A (C(4)H(10)O) has two enantiomeric forms and on d...

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