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tert-Butyl chloride on treatment with so...

tert-Butyl chloride on treatment with sodium alkoxide yields

A

an ether

B

an alkene

C

an alcohol

D

an alkyne

Text Solution

Verified by Experts

The correct Answer is:
B
NA
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tert-Butyl chloride on treatment with LiAlH_4 gives 2-methylpropene but with NaBH_4 it gives 2-methylpropane . Why so ? Explain.

Ethers can be prepared byWilliamson synthesis in which an alkyl halide is reacted with sodium alkoxide. Di - tert butyl ether cannot be prepare by this method. Explain.

Knowledge Check

  • Tert-butyl bromide on treatment with sodium methoxide yields

    A
    sodium tertiary butoxide
    B
    methyl tertiary butyl ether
    C
    tert-butyl alcohol
    D
    iso-butylene

  • Assertion: tert-Butyl chloride on treatment with sodium metal in dry ether gives 2,2,3,3-tetramethylbutane. Reason: tert-Alkyl halides readily undergo Wurtz reaction.

    A
    If both assertionn and reason are true, and reason is the true explanation of the assertion.
    B
    If both assertion and reason are true, but reason is not the true explanation of the assertion.
    C
    If assertion is true, but reason is false.
    D
    If both assertion and Reason are false.

  • (A) Di-tert-butyl ether cannot be prepared by Williamson's ether synethesis. (R ) tert-Butyl bromide on treatment with sodium tert-butoxide preferentially undergoes elimination to form isobutylene and tert-butyl alcohol

    A
    If both (A) and (R ) are correct and (R ) is correct explanation of (A ).
    B
    If both (A ) and (R ) are correct but (R ) is not correct explanation of (A ).
    C
    If (A) is correct but (R ) is incorrect
    D
    If (A) is incorrect but (R ) is correct.

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    tert-Butyl methyl ether on treatment with hydrogen iodide in cold gives ___________.

    The almost exclusive product obtained when tert-butyl bromide is heated with sodium ethoxdie is

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